2-exo,5-endo,8,8,10-Penta­chloro­bornane

The title compound, C(10)H(13)Cl(5), is a polychlorinated monoterpene and a Toxaphene congener. This compound is also the only penta­chlorinated derivative of camphene formed via ionic chlorination. Previously, the title compound was thought to be 2-exo,5-endo,9,9,10-penta­chloro­bornane, but X-ray...

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Detalles Bibliográficos
Autores principales: Valkonen, Arto, Kolehmainen, Erkki, Nikiforov, Vladimir
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961057/
https://www.ncbi.nlm.nih.gov/pubmed/21202080
http://dx.doi.org/10.1107/S1600536808006235
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author Valkonen, Arto
Kolehmainen, Erkki
Nikiforov, Vladimir
author_facet Valkonen, Arto
Kolehmainen, Erkki
Nikiforov, Vladimir
author_sort Valkonen, Arto
collection PubMed
description The title compound, C(10)H(13)Cl(5), is a polychlorinated monoterpene and a Toxaphene congener. This compound is also the only penta­chlorinated derivative of camphene formed via ionic chlorination. Previously, the title compound was thought to be 2-exo,5-endo,9,9,10-penta­chloro­bornane, but X-ray structural analysis showed it to have a different structure and rather to be 2-exo,5-endo,8,8,10-penta­chloro­bornane. The title compound shows static disorder and almost half the molecule was divided in two partitions with an occupancy ratio of 0.575 (major) to 0.425 (minor). The repulsive close contacts of Cl atoms could possibly be the cause for this disorder.
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spelling pubmed-29610572010-12-30 2-exo,5-endo,8,8,10-Penta­chloro­bornane Valkonen, Arto Kolehmainen, Erkki Nikiforov, Vladimir Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(10)H(13)Cl(5), is a polychlorinated monoterpene and a Toxaphene congener. This compound is also the only penta­chlorinated derivative of camphene formed via ionic chlorination. Previously, the title compound was thought to be 2-exo,5-endo,9,9,10-penta­chloro­bornane, but X-ray structural analysis showed it to have a different structure and rather to be 2-exo,5-endo,8,8,10-penta­chloro­bornane. The title compound shows static disorder and almost half the molecule was divided in two partitions with an occupancy ratio of 0.575 (major) to 0.425 (minor). The repulsive close contacts of Cl atoms could possibly be the cause for this disorder. International Union of Crystallography 2008-03-12 /pmc/articles/PMC2961057/ /pubmed/21202080 http://dx.doi.org/10.1107/S1600536808006235 Text en © Valkonen et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Valkonen, Arto
Kolehmainen, Erkki
Nikiforov, Vladimir
2-exo,5-endo,8,8,10-Penta­chloro­bornane
title 2-exo,5-endo,8,8,10-Penta­chloro­bornane
title_full 2-exo,5-endo,8,8,10-Penta­chloro­bornane
title_fullStr 2-exo,5-endo,8,8,10-Penta­chloro­bornane
title_full_unstemmed 2-exo,5-endo,8,8,10-Penta­chloro­bornane
title_short 2-exo,5-endo,8,8,10-Penta­chloro­bornane
title_sort 2-exo,5-endo,8,8,10-penta­chloro­bornane
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961057/
https://www.ncbi.nlm.nih.gov/pubmed/21202080
http://dx.doi.org/10.1107/S1600536808006235
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AT nikiforovvladimir 2exo5endo8810pentachlorobornane

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