Aqua­dicrotonato(di-2-pyridyl­amine)cobalt(II)

The Co atom in the title complex, [Co(CH(3)CHCHCOO)(2)(C(10)H(9)N(3))(H(2)O)], has a distorted recta­ngular–pyramidal geometry formed by the chelating dipyridylamine ligand, and two O atoms of monodentate carboxyl­ate groups of two different crotonate anions and a water molecule. The complex forms a...

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Detalles Bibliográficos
Autor principal: Wu, Jian
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961059/
https://www.ncbi.nlm.nih.gov/pubmed/21202037
http://dx.doi.org/10.1107/S1600536808008118
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author Wu, Jian
author_facet Wu, Jian
author_sort Wu, Jian
collection PubMed
description The Co atom in the title complex, [Co(CH(3)CHCHCOO)(2)(C(10)H(9)N(3))(H(2)O)], has a distorted recta­ngular–pyramidal geometry formed by the chelating dipyridylamine ligand, and two O atoms of monodentate carboxyl­ate groups of two different crotonate anions and a water molecule. The complex forms a three-dimensional supra­molecular network via inter­molecular O—H⋯O, N—H⋯O and C—H⋯O hydrogen-bonding contacts.
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spelling pubmed-29610592010-12-30 Aqua­dicrotonato(di-2-pyridyl­amine)cobalt(II) Wu, Jian Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Co atom in the title complex, [Co(CH(3)CHCHCOO)(2)(C(10)H(9)N(3))(H(2)O)], has a distorted recta­ngular–pyramidal geometry formed by the chelating dipyridylamine ligand, and two O atoms of monodentate carboxyl­ate groups of two different crotonate anions and a water molecule. The complex forms a three-dimensional supra­molecular network via inter­molecular O—H⋯O, N—H⋯O and C—H⋯O hydrogen-bonding contacts. International Union of Crystallography 2008-03-29 /pmc/articles/PMC2961059/ /pubmed/21202037 http://dx.doi.org/10.1107/S1600536808008118 Text en © Jian Wu 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wu, Jian
Aqua­dicrotonato(di-2-pyridyl­amine)cobalt(II)
title Aqua­dicrotonato(di-2-pyridyl­amine)cobalt(II)
title_full Aqua­dicrotonato(di-2-pyridyl­amine)cobalt(II)
title_fullStr Aqua­dicrotonato(di-2-pyridyl­amine)cobalt(II)
title_full_unstemmed Aqua­dicrotonato(di-2-pyridyl­amine)cobalt(II)
title_short Aqua­dicrotonato(di-2-pyridyl­amine)cobalt(II)
title_sort aqua­dicrotonato(di-2-pyridyl­amine)cobalt(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961059/
https://www.ncbi.nlm.nih.gov/pubmed/21202037
http://dx.doi.org/10.1107/S1600536808008118
work_keys_str_mv AT wujian aquadicrotonatodi2pyridylaminecobaltii

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