N′-(3-Thienylmethyl­ene)pyridine-2-carbohydrazide

The title compound, C(11)H(9)N(3)OS, was prepared to investigate the coordination chemistry of thio­phene-containing ligands as precursors to inter­esting metallopolymers. The mol­ecule is nearly planar. The angle between the thio­phene and pyridine rings is 8.63 (4)° and features the expected trans...

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Detalles Bibliográficos
Autores principales: Cheng, Haojin, Djukic, Brandon, Harrington, Laura E., Britten, James F., Lemaire, Martin T.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961063/
https://www.ncbi.nlm.nih.gov/pubmed/21202109
http://dx.doi.org/10.1107/S1600536808004960
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author Cheng, Haojin
Djukic, Brandon
Harrington, Laura E.
Britten, James F.
Lemaire, Martin T.
author_facet Cheng, Haojin
Djukic, Brandon
Harrington, Laura E.
Britten, James F.
Lemaire, Martin T.
author_sort Cheng, Haojin
collection PubMed
description The title compound, C(11)H(9)N(3)OS, was prepared to investigate the coordination chemistry of thio­phene-containing ligands as precursors to inter­esting metallopolymers. The mol­ecule is nearly planar. The angle between the thio­phene and pyridine rings is 8.63 (4)° and features the expected trans configuration about the imine bond. The structure is stabilized by a weak inter­molecular N—H⋯O hydrogen bond. The distance between centroids of adjacent thio­phene rings [3.67 (8) Å] suggests the presence of π–π inter­actions.
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spelling pubmed-29610632010-12-30 N′-(3-Thienylmethyl­ene)pyridine-2-carbohydrazide Cheng, Haojin Djukic, Brandon Harrington, Laura E. Britten, James F. Lemaire, Martin T. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(11)H(9)N(3)OS, was prepared to investigate the coordination chemistry of thio­phene-containing ligands as precursors to inter­esting metallopolymers. The mol­ecule is nearly planar. The angle between the thio­phene and pyridine rings is 8.63 (4)° and features the expected trans configuration about the imine bond. The structure is stabilized by a weak inter­molecular N—H⋯O hydrogen bond. The distance between centroids of adjacent thio­phene rings [3.67 (8) Å] suggests the presence of π–π inter­actions. International Union of Crystallography 2008-03-14 /pmc/articles/PMC2961063/ /pubmed/21202109 http://dx.doi.org/10.1107/S1600536808004960 Text en © Cheng et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Cheng, Haojin
Djukic, Brandon
Harrington, Laura E.
Britten, James F.
Lemaire, Martin T.
N′-(3-Thienylmethyl­ene)pyridine-2-carbohydrazide
title N′-(3-Thienylmethyl­ene)pyridine-2-carbohydrazide
title_full N′-(3-Thienylmethyl­ene)pyridine-2-carbohydrazide
title_fullStr N′-(3-Thienylmethyl­ene)pyridine-2-carbohydrazide
title_full_unstemmed N′-(3-Thienylmethyl­ene)pyridine-2-carbohydrazide
title_short N′-(3-Thienylmethyl­ene)pyridine-2-carbohydrazide
title_sort n′-(3-thienylmethyl­ene)pyridine-2-carbohydrazide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961063/
https://www.ncbi.nlm.nih.gov/pubmed/21202109
http://dx.doi.org/10.1107/S1600536808004960
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AT brittenjamesf n3thienylmethylenepyridine2carbohydrazide
AT lemairemartint n3thienylmethylenepyridine2carbohydrazide

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