2,4,6-Triamino-1,3,5-triazine-1,3-diium aqua­penta­fluoridoaluminate

The title compound, (C(3)H(8)N(6))[AlF(5)(H(2)O)], was obtained by solvothermal synthesis from the reaction of aluminium hydroxide, 1,3,5-triazine-2,4,6-triamine (melamine), aqueous HF and water at 323 K for 48 h. The structure consists of [AlF(5)(H(2)O)](2−) octa­hedra and diprotonated melaminium c...

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Detalles Bibliográficos
Autores principales: Cadiau, A., Hemon-Ribaud, A., Leblanc, M., Maisonneuve, V.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961066/
https://www.ncbi.nlm.nih.gov/pubmed/21201990
http://dx.doi.org/10.1107/S1600536808004091
Descripción
Sumario:The title compound, (C(3)H(8)N(6))[AlF(5)(H(2)O)], was obtained by solvothermal synthesis from the reaction of aluminium hydroxide, 1,3,5-triazine-2,4,6-triamine (melamine), aqueous HF and water at 323 K for 48 h. The structure consists of [AlF(5)(H(2)O)](2−) octa­hedra and diprotonated melaminium cations. Cohesion is ensured by a three-dimensional network of hydrogen bonds.

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