Bis(4,4′-methyl­enedianilinium) naphthalene-1,5-disulfonate dihydrate

The asymmetric unit of the title salt, C(13)H(16)N(2) (2+)·C(10)H(6)O(6)S(2) (2−)·2H(2)O, consists of one dication located on a general position, half each of two centrosymmetric dianions, and two uncoordinated water mol­ecules in general positions. In the dication, the dihedral angle between the be...

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Autor principal: Wei, Lin-Heng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961067/
https://www.ncbi.nlm.nih.gov/pubmed/21202124
http://dx.doi.org/10.1107/S160053680800723X
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author Wei, Lin-Heng
author_facet Wei, Lin-Heng
author_sort Wei, Lin-Heng
collection PubMed
description The asymmetric unit of the title salt, C(13)H(16)N(2) (2+)·C(10)H(6)O(6)S(2) (2−)·2H(2)O, consists of one dication located on a general position, half each of two centrosymmetric dianions, and two uncoordinated water mol­ecules in general positions. In the dication, the dihedral angle between the benzene rings is 74.67 (6)°. The cations and anions inter­act through N—H⋯O hydrogen bonds. The NH(3) (+) functional groups are also involved in N—H⋯O hydrogen bonds with the water mol­ecules, forming an infinite three-dimensional framework in the crystal structure.
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spelling pubmed-29610672010-12-30 Bis(4,4′-methyl­enedianilinium) naphthalene-1,5-disulfonate dihydrate Wei, Lin-Heng Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title salt, C(13)H(16)N(2) (2+)·C(10)H(6)O(6)S(2) (2−)·2H(2)O, consists of one dication located on a general position, half each of two centrosymmetric dianions, and two uncoordinated water mol­ecules in general positions. In the dication, the dihedral angle between the benzene rings is 74.67 (6)°. The cations and anions inter­act through N—H⋯O hydrogen bonds. The NH(3) (+) functional groups are also involved in N—H⋯O hydrogen bonds with the water mol­ecules, forming an infinite three-dimensional framework in the crystal structure. International Union of Crystallography 2008-03-20 /pmc/articles/PMC2961067/ /pubmed/21202124 http://dx.doi.org/10.1107/S160053680800723X Text en © Lin-Heng Wei 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Wei, Lin-Heng
Bis(4,4′-methyl­enedianilinium) naphthalene-1,5-disulfonate dihydrate
title Bis(4,4′-methyl­enedianilinium) naphthalene-1,5-disulfonate dihydrate
title_full Bis(4,4′-methyl­enedianilinium) naphthalene-1,5-disulfonate dihydrate
title_fullStr Bis(4,4′-methyl­enedianilinium) naphthalene-1,5-disulfonate dihydrate
title_full_unstemmed Bis(4,4′-methyl­enedianilinium) naphthalene-1,5-disulfonate dihydrate
title_short Bis(4,4′-methyl­enedianilinium) naphthalene-1,5-disulfonate dihydrate
title_sort bis(4,4′-methyl­enedianilinium) naphthalene-1,5-disulfonate dihydrate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961067/
https://www.ncbi.nlm.nih.gov/pubmed/21202124
http://dx.doi.org/10.1107/S160053680800723X
work_keys_str_mv AT weilinheng bis44methylenedianiliniumnaphthalene15disulfonatedihydrate

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