{4-Bromo-2-[2-(isopropyl­amino)ethyl­imino­meth­yl]phenolato}thio­cyanato­copper(II)

In the title mononuclear Schiff base copper(II) complex, [Cu(C(12)H(16)BrN(2)O)(NCS)], the Cu(II) ion is coordinated by two N atoms and one O atom from a Schiff base ligand, and by one N atom from a thio­cyanate anion, giving a square-planar geometry. There are long-range inter­actions between the C...

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Detalles Bibliográficos
Autores principales: Ma, Jun-Ying, He, Yin-Ting
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961070/
https://www.ncbi.nlm.nih.gov/pubmed/21202223
http://dx.doi.org/10.1107/S1600536808010404
Descripción
Sumario:In the title mononuclear Schiff base copper(II) complex, [Cu(C(12)H(16)BrN(2)O)(NCS)], the Cu(II) ion is coordinated by two N atoms and one O atom from a Schiff base ligand, and by one N atom from a thio­cyanate anion, giving a square-planar geometry. There are long-range inter­actions between the Cu atom and S [3.151 (5) Å] and Br [3.929 (5) Å] atoms above and below the square plane.

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