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Bis(μ-2,2′-oxydibenzoato-κ(4) O,O′:O′′,O′′′)bis[(4,4′-dimethyl-2,2′-bipyridine-κ(2) N,N′)zinc(II)] dihydrate
In the title compound, [Zn(2)(C(14)H(8)O(5))(2)(C(12)H(12)N(2))(2)]·2H(2)O, the Zn(II) atom exhibits a distorted octahedral coordination geometry, defined by two N atoms from one 4,4′-dimethyl-2,2′-bipyridine ligand and four O atoms from two bridging 2,2′-oxydibenzoate ligands. The molecule is a c...
| Autores principales: | , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2008
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961073/ https://www.ncbi.nlm.nih.gov/pubmed/21202231 http://dx.doi.org/10.1107/S1600536808010271 |
| _version_ | 1782188894670815232 |
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| author | Cui, Hong Li, Wen-Juan Tao, Ruo-Jie |
| author_facet | Cui, Hong Li, Wen-Juan Tao, Ruo-Jie |
| author_sort | Cui, Hong |
| collection | PubMed |
| description | In the title compound, [Zn(2)(C(14)H(8)O(5))(2)(C(12)H(12)N(2))(2)]·2H(2)O, the Zn(II) atom exhibits a distorted octahedral coordination geometry, defined by two N atoms from one 4,4′-dimethyl-2,2′-bipyridine ligand and four O atoms from two bridging 2,2′-oxydibenzoate ligands. The molecule is a centrosymmetric dimer. π–π Stacking interactions are observed between the 4,4′-dimethyl-2,2′-bipyridine ligands, with a centroid–centroid distance of 3.649 (2) Å. |
| format | Text |
| id | pubmed-2961073 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2008 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29610732010-12-30 Bis(μ-2,2′-oxydibenzoato-κ(4) O,O′:O′′,O′′′)bis[(4,4′-dimethyl-2,2′-bipyridine-κ(2) N,N′)zinc(II)] dihydrate Cui, Hong Li, Wen-Juan Tao, Ruo-Jie Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Zn(2)(C(14)H(8)O(5))(2)(C(12)H(12)N(2))(2)]·2H(2)O, the Zn(II) atom exhibits a distorted octahedral coordination geometry, defined by two N atoms from one 4,4′-dimethyl-2,2′-bipyridine ligand and four O atoms from two bridging 2,2′-oxydibenzoate ligands. The molecule is a centrosymmetric dimer. π–π Stacking interactions are observed between the 4,4′-dimethyl-2,2′-bipyridine ligands, with a centroid–centroid distance of 3.649 (2) Å. International Union of Crystallography 2008-04-23 /pmc/articles/PMC2961073/ /pubmed/21202231 http://dx.doi.org/10.1107/S1600536808010271 Text en © Cui et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Cui, Hong Li, Wen-Juan Tao, Ruo-Jie Bis(μ-2,2′-oxydibenzoato-κ(4) O,O′:O′′,O′′′)bis[(4,4′-dimethyl-2,2′-bipyridine-κ(2) N,N′)zinc(II)] dihydrate |
| title | Bis(μ-2,2′-oxydibenzoato-κ(4)
O,O′:O′′,O′′′)bis[(4,4′-dimethyl-2,2′-bipyridine-κ(2)
N,N′)zinc(II)] dihydrate |
| title_full | Bis(μ-2,2′-oxydibenzoato-κ(4)
O,O′:O′′,O′′′)bis[(4,4′-dimethyl-2,2′-bipyridine-κ(2)
N,N′)zinc(II)] dihydrate |
| title_fullStr | Bis(μ-2,2′-oxydibenzoato-κ(4)
O,O′:O′′,O′′′)bis[(4,4′-dimethyl-2,2′-bipyridine-κ(2)
N,N′)zinc(II)] dihydrate |
| title_full_unstemmed | Bis(μ-2,2′-oxydibenzoato-κ(4)
O,O′:O′′,O′′′)bis[(4,4′-dimethyl-2,2′-bipyridine-κ(2)
N,N′)zinc(II)] dihydrate |
| title_short | Bis(μ-2,2′-oxydibenzoato-κ(4)
O,O′:O′′,O′′′)bis[(4,4′-dimethyl-2,2′-bipyridine-κ(2)
N,N′)zinc(II)] dihydrate |
| title_sort | bis(μ-2,2′-oxydibenzoato-κ(4)
o,o′:o′′,o′′′)bis[(4,4′-dimethyl-2,2′-bipyridine-κ(2)
n,n′)zinc(ii)] dihydrate |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961073/ https://www.ncbi.nlm.nih.gov/pubmed/21202231 http://dx.doi.org/10.1107/S1600536808010271 |
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