Hydroxonium triaqua­bis(biuret-κ(2) O,O′)dichloridolanthanum(III) dichloride dihydrate

In the title compound, (H(3)O)[LaCl(2)(C(2)H(5)N(3)O(2))(2)(H(2)O)(3)]Cl(2)·2H(2)O, the La atom is bonded to seven O atoms (arising from two O,O′-bidentate biuret mol­ecules and three water mol­ecules) and two chloride ions in an irregular arrangement. A network of N—H⋯O, N—H⋯Cl, O—H⋯O and O—H⋯Cl hy...

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Detalles Bibliográficos
Autor principal: Harrison, William T. A.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961074/
https://www.ncbi.nlm.nih.gov/pubmed/21202219
http://dx.doi.org/10.1107/S1600536808010349
Descripción
Sumario:In the title compound, (H(3)O)[LaCl(2)(C(2)H(5)N(3)O(2))(2)(H(2)O)(3)]Cl(2)·2H(2)O, the La atom is bonded to seven O atoms (arising from two O,O′-bidentate biuret mol­ecules and three water mol­ecules) and two chloride ions in an irregular arrangement. A network of N—H⋯O, N—H⋯Cl, O—H⋯O and O—H⋯Cl hydrogen bonds helps to establish the packing, leading to a three-dimensional network. The La atom, one Cl atom and four O atoms lie on a crystallographic mirror plane.

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