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Hydroxonium triaqua­bis(biuret-κ(2) O,O′)dichloridolanthanum(III) dichloride dihydrate

In the title compound, (H(3)O)[LaCl(2)(C(2)H(5)N(3)O(2))(2)(H(2)O)(3)]Cl(2)·2H(2)O, the La atom is bonded to seven O atoms (arising from two O,O′-bidentate biuret mol­ecules and three water mol­ecules) and two chloride ions in an irregular arrangement. A network of N—H⋯O, N—H⋯Cl, O—H⋯O and O—H⋯Cl hy...

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Detalles Bibliográficos
Autor principal: Harrison, William T. A.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961074/
https://www.ncbi.nlm.nih.gov/pubmed/21202219
http://dx.doi.org/10.1107/S1600536808010349
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author Harrison, William T. A.
author_facet Harrison, William T. A.
author_sort Harrison, William T. A.
collection PubMed
description In the title compound, (H(3)O)[LaCl(2)(C(2)H(5)N(3)O(2))(2)(H(2)O)(3)]Cl(2)·2H(2)O, the La atom is bonded to seven O atoms (arising from two O,O′-bidentate biuret mol­ecules and three water mol­ecules) and two chloride ions in an irregular arrangement. A network of N—H⋯O, N—H⋯Cl, O—H⋯O and O—H⋯Cl hydrogen bonds helps to establish the packing, leading to a three-dimensional network. The La atom, one Cl atom and four O atoms lie on a crystallographic mirror plane.
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spelling pubmed-29610742010-12-30 Hydroxonium triaqua­bis(biuret-κ(2) O,O′)dichloridolanthanum(III) dichloride dihydrate Harrison, William T. A. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, (H(3)O)[LaCl(2)(C(2)H(5)N(3)O(2))(2)(H(2)O)(3)]Cl(2)·2H(2)O, the La atom is bonded to seven O atoms (arising from two O,O′-bidentate biuret mol­ecules and three water mol­ecules) and two chloride ions in an irregular arrangement. A network of N—H⋯O, N—H⋯Cl, O—H⋯O and O—H⋯Cl hydrogen bonds helps to establish the packing, leading to a three-dimensional network. The La atom, one Cl atom and four O atoms lie on a crystallographic mirror plane. International Union of Crystallography 2008-04-18 /pmc/articles/PMC2961074/ /pubmed/21202219 http://dx.doi.org/10.1107/S1600536808010349 Text en © William T. A. Harrison 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Harrison, William T. A.
Hydroxonium triaqua­bis(biuret-κ(2) O,O′)dichloridolanthanum(III) dichloride dihydrate
title Hydroxonium triaqua­bis(biuret-κ(2) O,O′)dichloridolanthanum(III) dichloride dihydrate
title_full Hydroxonium triaqua­bis(biuret-κ(2) O,O′)dichloridolanthanum(III) dichloride dihydrate
title_fullStr Hydroxonium triaqua­bis(biuret-κ(2) O,O′)dichloridolanthanum(III) dichloride dihydrate
title_full_unstemmed Hydroxonium triaqua­bis(biuret-κ(2) O,O′)dichloridolanthanum(III) dichloride dihydrate
title_short Hydroxonium triaqua­bis(biuret-κ(2) O,O′)dichloridolanthanum(III) dichloride dihydrate
title_sort hydroxonium triaqua­bis(biuret-κ(2) o,o′)dichloridolanthanum(iii) dichloride dihydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961074/
https://www.ncbi.nlm.nih.gov/pubmed/21202219
http://dx.doi.org/10.1107/S1600536808010349
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