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Bis(2-amino­pyrimidine-κN (1))dibromidozinc(II)

The title compound, [ZnBr(2)(C(4)H(5)N(3))(2)], is a mononuclear complex in which the Zn(II) ions have distorted tetra­hedral coordination geometry. The Zn(II) ion binds to two N atoms from two different 2-amino­pyrimidine ligands and two bromide ions. N—H⋯N hydrogen bonds link the mol­ecules to for...

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Detalles Bibliográficos
Autores principales: Qu, Yang, Zhang, Shi Ming, Wu, Xian Zong, Zhang, Huan, Lin, Zhi Dong
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961077/
https://www.ncbi.nlm.nih.gov/pubmed/21202255
http://dx.doi.org/10.1107/S1600536808006466
Descripción
Sumario:The title compound, [ZnBr(2)(C(4)H(5)N(3))(2)], is a mononuclear complex in which the Zn(II) ions have distorted tetra­hedral coordination geometry. The Zn(II) ion binds to two N atoms from two different 2-amino­pyrimidine ligands and two bromide ions. N—H⋯N hydrogen bonds link the mol­ecules to form a one-dimensional supra­molecular structure. The supra­molecular chains are parallel to each other and N—H⋯Br hydrogen bonds link them into a two-dimensional network in the ac plane. Additionally, there are strong π–π inter­actions [centroid–centroid distance = 3.403 (3) Å].