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Bis(2-aminopyrimidine-κN (1))dibromidozinc(II)
The title compound, [ZnBr(2)(C(4)H(5)N(3))(2)], is a mononuclear complex in which the Zn(II) ions have distorted tetrahedral coordination geometry. The Zn(II) ion binds to two N atoms from two different 2-aminopyrimidine ligands and two bromide ions. N—H⋯N hydrogen bonds link the molecules to for...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961077/ https://www.ncbi.nlm.nih.gov/pubmed/21202255 http://dx.doi.org/10.1107/S1600536808006466 |
Sumario: | The title compound, [ZnBr(2)(C(4)H(5)N(3))(2)], is a mononuclear complex in which the Zn(II) ions have distorted tetrahedral coordination geometry. The Zn(II) ion binds to two N atoms from two different 2-aminopyrimidine ligands and two bromide ions. N—H⋯N hydrogen bonds link the molecules to form a one-dimensional supramolecular structure. The supramolecular chains are parallel to each other and N—H⋯Br hydrogen bonds link them into a two-dimensional network in the ac plane. Additionally, there are strong π–π interactions [centroid–centroid distance = 3.403 (3) Å]. |
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