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Bis(2-amino­pyrimidine-κN (1))dibromidozinc(II)

The title compound, [ZnBr(2)(C(4)H(5)N(3))(2)], is a mononuclear complex in which the Zn(II) ions have distorted tetra­hedral coordination geometry. The Zn(II) ion binds to two N atoms from two different 2-amino­pyrimidine ligands and two bromide ions. N—H⋯N hydrogen bonds link the mol­ecules to for...

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Detalles Bibliográficos
Autores principales: Qu, Yang, Zhang, Shi Ming, Wu, Xian Zong, Zhang, Huan, Lin, Zhi Dong
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961077/
https://www.ncbi.nlm.nih.gov/pubmed/21202255
http://dx.doi.org/10.1107/S1600536808006466
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author Qu, Yang
Zhang, Shi Ming
Wu, Xian Zong
Zhang, Huan
Lin, Zhi Dong
author_facet Qu, Yang
Zhang, Shi Ming
Wu, Xian Zong
Zhang, Huan
Lin, Zhi Dong
author_sort Qu, Yang
collection PubMed
description The title compound, [ZnBr(2)(C(4)H(5)N(3))(2)], is a mononuclear complex in which the Zn(II) ions have distorted tetra­hedral coordination geometry. The Zn(II) ion binds to two N atoms from two different 2-amino­pyrimidine ligands and two bromide ions. N—H⋯N hydrogen bonds link the mol­ecules to form a one-dimensional supra­molecular structure. The supra­molecular chains are parallel to each other and N—H⋯Br hydrogen bonds link them into a two-dimensional network in the ac plane. Additionally, there are strong π–π inter­actions [centroid–centroid distance = 3.403 (3) Å].
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spelling pubmed-29610772010-12-30 Bis(2-amino­pyrimidine-κN (1))dibromidozinc(II) Qu, Yang Zhang, Shi Ming Wu, Xian Zong Zhang, Huan Lin, Zhi Dong Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [ZnBr(2)(C(4)H(5)N(3))(2)], is a mononuclear complex in which the Zn(II) ions have distorted tetra­hedral coordination geometry. The Zn(II) ion binds to two N atoms from two different 2-amino­pyrimidine ligands and two bromide ions. N—H⋯N hydrogen bonds link the mol­ecules to form a one-dimensional supra­molecular structure. The supra­molecular chains are parallel to each other and N—H⋯Br hydrogen bonds link them into a two-dimensional network in the ac plane. Additionally, there are strong π–π inter­actions [centroid–centroid distance = 3.403 (3) Å]. International Union of Crystallography 2008-04-30 /pmc/articles/PMC2961077/ /pubmed/21202255 http://dx.doi.org/10.1107/S1600536808006466 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html.
spellingShingle Metal-Organic Papers
Qu, Yang
Zhang, Shi Ming
Wu, Xian Zong
Zhang, Huan
Lin, Zhi Dong
Bis(2-amino­pyrimidine-κN (1))dibromidozinc(II)
title Bis(2-amino­pyrimidine-κN (1))dibromidozinc(II)
title_full Bis(2-amino­pyrimidine-κN (1))dibromidozinc(II)
title_fullStr Bis(2-amino­pyrimidine-κN (1))dibromidozinc(II)
title_full_unstemmed Bis(2-amino­pyrimidine-κN (1))dibromidozinc(II)
title_short Bis(2-amino­pyrimidine-κN (1))dibromidozinc(II)
title_sort bis(2-amino­pyrimidine-κn (1))dibromidozinc(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961077/
https://www.ncbi.nlm.nih.gov/pubmed/21202255
http://dx.doi.org/10.1107/S1600536808006466
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