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Bis(2-aminopyrimidine-κN (1))dibromidozinc(II)
The title compound, [ZnBr(2)(C(4)H(5)N(3))(2)], is a mononuclear complex in which the Zn(II) ions have distorted tetrahedral coordination geometry. The Zn(II) ion binds to two N atoms from two different 2-aminopyrimidine ligands and two bromide ions. N—H⋯N hydrogen bonds link the molecules to for...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961077/ https://www.ncbi.nlm.nih.gov/pubmed/21202255 http://dx.doi.org/10.1107/S1600536808006466 |
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author | Qu, Yang Zhang, Shi Ming Wu, Xian Zong Zhang, Huan Lin, Zhi Dong |
author_facet | Qu, Yang Zhang, Shi Ming Wu, Xian Zong Zhang, Huan Lin, Zhi Dong |
author_sort | Qu, Yang |
collection | PubMed |
description | The title compound, [ZnBr(2)(C(4)H(5)N(3))(2)], is a mononuclear complex in which the Zn(II) ions have distorted tetrahedral coordination geometry. The Zn(II) ion binds to two N atoms from two different 2-aminopyrimidine ligands and two bromide ions. N—H⋯N hydrogen bonds link the molecules to form a one-dimensional supramolecular structure. The supramolecular chains are parallel to each other and N—H⋯Br hydrogen bonds link them into a two-dimensional network in the ac plane. Additionally, there are strong π–π interactions [centroid–centroid distance = 3.403 (3) Å]. |
format | Text |
id | pubmed-2961077 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29610772010-12-30 Bis(2-aminopyrimidine-κN (1))dibromidozinc(II) Qu, Yang Zhang, Shi Ming Wu, Xian Zong Zhang, Huan Lin, Zhi Dong Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [ZnBr(2)(C(4)H(5)N(3))(2)], is a mononuclear complex in which the Zn(II) ions have distorted tetrahedral coordination geometry. The Zn(II) ion binds to two N atoms from two different 2-aminopyrimidine ligands and two bromide ions. N—H⋯N hydrogen bonds link the molecules to form a one-dimensional supramolecular structure. The supramolecular chains are parallel to each other and N—H⋯Br hydrogen bonds link them into a two-dimensional network in the ac plane. Additionally, there are strong π–π interactions [centroid–centroid distance = 3.403 (3) Å]. International Union of Crystallography 2008-04-30 /pmc/articles/PMC2961077/ /pubmed/21202255 http://dx.doi.org/10.1107/S1600536808006466 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html. |
spellingShingle | Metal-Organic Papers Qu, Yang Zhang, Shi Ming Wu, Xian Zong Zhang, Huan Lin, Zhi Dong Bis(2-aminopyrimidine-κN (1))dibromidozinc(II) |
title | Bis(2-aminopyrimidine-κN
(1))dibromidozinc(II) |
title_full | Bis(2-aminopyrimidine-κN
(1))dibromidozinc(II) |
title_fullStr | Bis(2-aminopyrimidine-κN
(1))dibromidozinc(II) |
title_full_unstemmed | Bis(2-aminopyrimidine-κN
(1))dibromidozinc(II) |
title_short | Bis(2-aminopyrimidine-κN
(1))dibromidozinc(II) |
title_sort | bis(2-aminopyrimidine-κn
(1))dibromidozinc(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961077/ https://www.ncbi.nlm.nih.gov/pubmed/21202255 http://dx.doi.org/10.1107/S1600536808006466 |
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