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Bis(chloroacetato)-κ(2) O,O′;κO-methanol-κO-bis(2-methylfuro[3,2-c]pyridine-κN)copper(II)
In the title compound, [Cu(C(2)H(2)ClO(2))(2)(C(8)H(7)NO)(2)(CH(4)O)], the Cu(2+) ion has a highly distorted square-bipyramidal (4 + 1 + 1) coordination environment and is bonded to three carboxylate O atoms of two chloroacetate anions (monodentate and asymmetrically bidentate), two pyridine N ato...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961079/ https://www.ncbi.nlm.nih.gov/pubmed/21202169 http://dx.doi.org/10.1107/S1600536808008404 |
Sumario: | In the title compound, [Cu(C(2)H(2)ClO(2))(2)(C(8)H(7)NO)(2)(CH(4)O)], the Cu(2+) ion has a highly distorted square-bipyramidal (4 + 1 + 1) coordination environment and is bonded to three carboxylate O atoms of two chloroacetate anions (monodentate and asymmetrically bidentate), two pyridine N atoms of 2-methylfuro[3,2-c]pyridine and one methanol O atom. There is an intramolecular O—H⋯O hydrogen bond. Intermolecular C—H⋯O hydrogen bonds result in the formation of a three-dimensional network and π–π stacking interactions [3.44–3.83 Å] are observed between symmetry-related rings of 2-methylfuro[3,2-c]pyridine. Further interactions in the crystal structure are a short Cl⋯Cl interaction [3.384 (2)Å] and C—H⋯π interactions between 2-methylfuro[3,2-c]pyridine rings. |
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