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Bis(chloro­acetato)-κ(2) O,O′;κO-methanol-κO-bis­(2-methyl­furo[3,2-c]pyridine-κN)copper(II)

In the title compound, [Cu(C(2)H(2)ClO(2))(2)(C(8)H(7)NO)(2)(CH(4)O)], the Cu(2+) ion has a highly distorted square-bipyramidal (4 + 1 + 1) coordination environment and is bonded to three carboxyl­ate O atoms of two chloro­acetate anions (monodentate and asymmetrically bidentate), two pyridine N ato...

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Detalles Bibliográficos
Autores principales: Mikloš, Dušan, Miklovič, Jozef, Mrázová, Viera, Moncol, Jan, Segľa, Peter
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961079/
https://www.ncbi.nlm.nih.gov/pubmed/21202169
http://dx.doi.org/10.1107/S1600536808008404
Descripción
Sumario:In the title compound, [Cu(C(2)H(2)ClO(2))(2)(C(8)H(7)NO)(2)(CH(4)O)], the Cu(2+) ion has a highly distorted square-bipyramidal (4 + 1 + 1) coordination environment and is bonded to three carboxyl­ate O atoms of two chloro­acetate anions (monodentate and asymmetrically bidentate), two pyridine N atoms of 2-methyl­furo[3,2-c]pyridine and one methanol O atom. There is an intra­molecular O—H⋯O hydrogen bond. Inter­molecular C—H⋯O hydrogen bonds result in the formation of a three-dimensional network and π–π stacking inter­actions [3.44–3.83 Å] are observed between symmetry-related rings of 2-methyl­furo[3,2-c]pyridine. Further inter­actions in the crystal structure are a short Cl⋯Cl inter­action [3.384 (2)Å] and C—H⋯π inter­actions between 2-methyl­furo[3,2-c]pyridine rings.