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Bis(chloroacetato)-κ(2) O,O′;κO-methanol-κO-bis(2-methylfuro[3,2-c]pyridine-κN)copper(II)
In the title compound, [Cu(C(2)H(2)ClO(2))(2)(C(8)H(7)NO)(2)(CH(4)O)], the Cu(2+) ion has a highly distorted square-bipyramidal (4 + 1 + 1) coordination environment and is bonded to three carboxylate O atoms of two chloroacetate anions (monodentate and asymmetrically bidentate), two pyridine N ato...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961079/ https://www.ncbi.nlm.nih.gov/pubmed/21202169 http://dx.doi.org/10.1107/S1600536808008404 |
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author | Mikloš, Dušan Miklovič, Jozef Mrázová, Viera Moncol, Jan Segľa, Peter |
author_facet | Mikloš, Dušan Miklovič, Jozef Mrázová, Viera Moncol, Jan Segľa, Peter |
author_sort | Mikloš, Dušan |
collection | PubMed |
description | In the title compound, [Cu(C(2)H(2)ClO(2))(2)(C(8)H(7)NO)(2)(CH(4)O)], the Cu(2+) ion has a highly distorted square-bipyramidal (4 + 1 + 1) coordination environment and is bonded to three carboxylate O atoms of two chloroacetate anions (monodentate and asymmetrically bidentate), two pyridine N atoms of 2-methylfuro[3,2-c]pyridine and one methanol O atom. There is an intramolecular O—H⋯O hydrogen bond. Intermolecular C—H⋯O hydrogen bonds result in the formation of a three-dimensional network and π–π stacking interactions [3.44–3.83 Å] are observed between symmetry-related rings of 2-methylfuro[3,2-c]pyridine. Further interactions in the crystal structure are a short Cl⋯Cl interaction [3.384 (2)Å] and C—H⋯π interactions between 2-methylfuro[3,2-c]pyridine rings. |
format | Text |
id | pubmed-2961079 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29610792010-12-30 Bis(chloroacetato)-κ(2) O,O′;κO-methanol-κO-bis(2-methylfuro[3,2-c]pyridine-κN)copper(II) Mikloš, Dušan Miklovič, Jozef Mrázová, Viera Moncol, Jan Segľa, Peter Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cu(C(2)H(2)ClO(2))(2)(C(8)H(7)NO)(2)(CH(4)O)], the Cu(2+) ion has a highly distorted square-bipyramidal (4 + 1 + 1) coordination environment and is bonded to three carboxylate O atoms of two chloroacetate anions (monodentate and asymmetrically bidentate), two pyridine N atoms of 2-methylfuro[3,2-c]pyridine and one methanol O atom. There is an intramolecular O—H⋯O hydrogen bond. Intermolecular C—H⋯O hydrogen bonds result in the formation of a three-dimensional network and π–π stacking interactions [3.44–3.83 Å] are observed between symmetry-related rings of 2-methylfuro[3,2-c]pyridine. Further interactions in the crystal structure are a short Cl⋯Cl interaction [3.384 (2)Å] and C—H⋯π interactions between 2-methylfuro[3,2-c]pyridine rings. International Union of Crystallography 2008-04-02 /pmc/articles/PMC2961079/ /pubmed/21202169 http://dx.doi.org/10.1107/S1600536808008404 Text en © Mikloš et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Mikloš, Dušan Miklovič, Jozef Mrázová, Viera Moncol, Jan Segľa, Peter Bis(chloroacetato)-κ(2) O,O′;κO-methanol-κO-bis(2-methylfuro[3,2-c]pyridine-κN)copper(II) |
title | Bis(chloroacetato)-κ(2)
O,O′;κO-methanol-κO-bis(2-methylfuro[3,2-c]pyridine-κN)copper(II) |
title_full | Bis(chloroacetato)-κ(2)
O,O′;κO-methanol-κO-bis(2-methylfuro[3,2-c]pyridine-κN)copper(II) |
title_fullStr | Bis(chloroacetato)-κ(2)
O,O′;κO-methanol-κO-bis(2-methylfuro[3,2-c]pyridine-κN)copper(II) |
title_full_unstemmed | Bis(chloroacetato)-κ(2)
O,O′;κO-methanol-κO-bis(2-methylfuro[3,2-c]pyridine-κN)copper(II) |
title_short | Bis(chloroacetato)-κ(2)
O,O′;κO-methanol-κO-bis(2-methylfuro[3,2-c]pyridine-κN)copper(II) |
title_sort | bis(chloroacetato)-κ(2)
o,o′;κo-methanol-κo-bis(2-methylfuro[3,2-c]pyridine-κn)copper(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961079/ https://www.ncbi.nlm.nih.gov/pubmed/21202169 http://dx.doi.org/10.1107/S1600536808008404 |
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