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Bis(chloro­acetato)-κ(2) O,O′;κO-methanol-κO-bis­(2-methyl­furo[3,2-c]pyridine-κN)copper(II)

In the title compound, [Cu(C(2)H(2)ClO(2))(2)(C(8)H(7)NO)(2)(CH(4)O)], the Cu(2+) ion has a highly distorted square-bipyramidal (4 + 1 + 1) coordination environment and is bonded to three carboxyl­ate O atoms of two chloro­acetate anions (monodentate and asymmetrically bidentate), two pyridine N ato...

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Detalles Bibliográficos
Autores principales: Mikloš, Dušan, Miklovič, Jozef, Mrázová, Viera, Moncol, Jan, Segľa, Peter
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961079/
https://www.ncbi.nlm.nih.gov/pubmed/21202169
http://dx.doi.org/10.1107/S1600536808008404
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author Mikloš, Dušan
Miklovič, Jozef
Mrázová, Viera
Moncol, Jan
Segľa, Peter
author_facet Mikloš, Dušan
Miklovič, Jozef
Mrázová, Viera
Moncol, Jan
Segľa, Peter
author_sort Mikloš, Dušan
collection PubMed
description In the title compound, [Cu(C(2)H(2)ClO(2))(2)(C(8)H(7)NO)(2)(CH(4)O)], the Cu(2+) ion has a highly distorted square-bipyramidal (4 + 1 + 1) coordination environment and is bonded to three carboxyl­ate O atoms of two chloro­acetate anions (monodentate and asymmetrically bidentate), two pyridine N atoms of 2-methyl­furo[3,2-c]pyridine and one methanol O atom. There is an intra­molecular O—H⋯O hydrogen bond. Inter­molecular C—H⋯O hydrogen bonds result in the formation of a three-dimensional network and π–π stacking inter­actions [3.44–3.83 Å] are observed between symmetry-related rings of 2-methyl­furo[3,2-c]pyridine. Further inter­actions in the crystal structure are a short Cl⋯Cl inter­action [3.384 (2)Å] and C—H⋯π inter­actions between 2-methyl­furo[3,2-c]pyridine rings.
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spelling pubmed-29610792010-12-30 Bis(chloro­acetato)-κ(2) O,O′;κO-methanol-κO-bis­(2-methyl­furo[3,2-c]pyridine-κN)copper(II) Mikloš, Dušan Miklovič, Jozef Mrázová, Viera Moncol, Jan Segľa, Peter Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cu(C(2)H(2)ClO(2))(2)(C(8)H(7)NO)(2)(CH(4)O)], the Cu(2+) ion has a highly distorted square-bipyramidal (4 + 1 + 1) coordination environment and is bonded to three carboxyl­ate O atoms of two chloro­acetate anions (monodentate and asymmetrically bidentate), two pyridine N atoms of 2-methyl­furo[3,2-c]pyridine and one methanol O atom. There is an intra­molecular O—H⋯O hydrogen bond. Inter­molecular C—H⋯O hydrogen bonds result in the formation of a three-dimensional network and π–π stacking inter­actions [3.44–3.83 Å] are observed between symmetry-related rings of 2-methyl­furo[3,2-c]pyridine. Further inter­actions in the crystal structure are a short Cl⋯Cl inter­action [3.384 (2)Å] and C—H⋯π inter­actions between 2-methyl­furo[3,2-c]pyridine rings. International Union of Crystallography 2008-04-02 /pmc/articles/PMC2961079/ /pubmed/21202169 http://dx.doi.org/10.1107/S1600536808008404 Text en © Mikloš et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Mikloš, Dušan
Miklovič, Jozef
Mrázová, Viera
Moncol, Jan
Segľa, Peter
Bis(chloro­acetato)-κ(2) O,O′;κO-methanol-κO-bis­(2-methyl­furo[3,2-c]pyridine-κN)copper(II)
title Bis(chloro­acetato)-κ(2) O,O′;κO-methanol-κO-bis­(2-methyl­furo[3,2-c]pyridine-κN)copper(II)
title_full Bis(chloro­acetato)-κ(2) O,O′;κO-methanol-κO-bis­(2-methyl­furo[3,2-c]pyridine-κN)copper(II)
title_fullStr Bis(chloro­acetato)-κ(2) O,O′;κO-methanol-κO-bis­(2-methyl­furo[3,2-c]pyridine-κN)copper(II)
title_full_unstemmed Bis(chloro­acetato)-κ(2) O,O′;κO-methanol-κO-bis­(2-methyl­furo[3,2-c]pyridine-κN)copper(II)
title_short Bis(chloro­acetato)-κ(2) O,O′;κO-methanol-κO-bis­(2-methyl­furo[3,2-c]pyridine-κN)copper(II)
title_sort bis(chloro­acetato)-κ(2) o,o′;κo-methanol-κo-bis­(2-methyl­furo[3,2-c]pyridine-κn)copper(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961079/
https://www.ncbi.nlm.nih.gov/pubmed/21202169
http://dx.doi.org/10.1107/S1600536808008404
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