Cargando…

Aqua­bis(1H-imidazole-κN (3))bis­(4-methyl­benzoato)-κO;κO,O′-nickel(II)

In the mononuclear title compound, [Ni(C(8)H(7)O(2))(2)(C(3)H(4)N(2))(2)(H(2)O)], the Ni(II) atom is coordinated by three carboxylate O atoms (from a bidentate 4-methyl­benzoate ligand and a monodentate 4-methyl­benzoate ligand), two N atoms (from two imidazole ligands) and a water mol­ecule in an o...

Descripción completa

Detalles Bibliográficos
Autores principales: Song, Wen-Dong, Fan, Run-Zhen, Wu, Hong-Mian
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961080/
https://www.ncbi.nlm.nih.gov/pubmed/21202196
http://dx.doi.org/10.1107/S1600536808009471
_version_ 1782188896655769600
author Song, Wen-Dong
Fan, Run-Zhen
Wu, Hong-Mian
author_facet Song, Wen-Dong
Fan, Run-Zhen
Wu, Hong-Mian
author_sort Song, Wen-Dong
collection PubMed
description In the mononuclear title compound, [Ni(C(8)H(7)O(2))(2)(C(3)H(4)N(2))(2)(H(2)O)], the Ni(II) atom is coordinated by three carboxylate O atoms (from a bidentate 4-methyl­benzoate ligand and a monodentate 4-methyl­benzoate ligand), two N atoms (from two imidazole ligands) and a water mol­ecule in an octa­hedral geometry. Inter­molecular O—H⋯O hydrogen-bonding inter­actions lead to infinite chains, which are further self-assembled into a supra­molecular network through inter­molecular N—H⋯O hydrogen-bonding inter­actions and π–π stacking [centroid–centroid distance = 3.717 (2) Å].
format Text
id pubmed-2961080
institution National Center for Biotechnology Information
language English
publishDate 2008
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29610802010-12-30 Aqua­bis(1H-imidazole-κN (3))bis­(4-methyl­benzoato)-κO;κO,O′-nickel(II) Song, Wen-Dong Fan, Run-Zhen Wu, Hong-Mian Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the mononuclear title compound, [Ni(C(8)H(7)O(2))(2)(C(3)H(4)N(2))(2)(H(2)O)], the Ni(II) atom is coordinated by three carboxylate O atoms (from a bidentate 4-methyl­benzoate ligand and a monodentate 4-methyl­benzoate ligand), two N atoms (from two imidazole ligands) and a water mol­ecule in an octa­hedral geometry. Inter­molecular O—H⋯O hydrogen-bonding inter­actions lead to infinite chains, which are further self-assembled into a supra­molecular network through inter­molecular N—H⋯O hydrogen-bonding inter­actions and π–π stacking [centroid–centroid distance = 3.717 (2) Å]. International Union of Crystallography 2008-04-10 /pmc/articles/PMC2961080/ /pubmed/21202196 http://dx.doi.org/10.1107/S1600536808009471 Text en © Song et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Song, Wen-Dong
Fan, Run-Zhen
Wu, Hong-Mian
Aqua­bis(1H-imidazole-κN (3))bis­(4-methyl­benzoato)-κO;κO,O′-nickel(II)
title Aqua­bis(1H-imidazole-κN (3))bis­(4-methyl­benzoato)-κO;κO,O′-nickel(II)
title_full Aqua­bis(1H-imidazole-κN (3))bis­(4-methyl­benzoato)-κO;κO,O′-nickel(II)
title_fullStr Aqua­bis(1H-imidazole-κN (3))bis­(4-methyl­benzoato)-κO;κO,O′-nickel(II)
title_full_unstemmed Aqua­bis(1H-imidazole-κN (3))bis­(4-methyl­benzoato)-κO;κO,O′-nickel(II)
title_short Aqua­bis(1H-imidazole-κN (3))bis­(4-methyl­benzoato)-κO;κO,O′-nickel(II)
title_sort aqua­bis(1h-imidazole-κn (3))bis­(4-methyl­benzoato)-κo;κo,o′-nickel(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961080/
https://www.ncbi.nlm.nih.gov/pubmed/21202196
http://dx.doi.org/10.1107/S1600536808009471
work_keys_str_mv AT songwendong aquabis1himidazolekn3bis4methylbenzoatokokoonickelii
AT fanrunzhen aquabis1himidazolekn3bis4methylbenzoatokokoonickelii
AT wuhongmian aquabis1himidazolekn3bis4methylbenzoatokokoonickelii