Cargando…
Aquabis(1H-imidazole-κN (3))bis(4-methylbenzoato)-κO;κO,O′-nickel(II)
In the mononuclear title compound, [Ni(C(8)H(7)O(2))(2)(C(3)H(4)N(2))(2)(H(2)O)], the Ni(II) atom is coordinated by three carboxylate O atoms (from a bidentate 4-methylbenzoate ligand and a monodentate 4-methylbenzoate ligand), two N atoms (from two imidazole ligands) and a water molecule in an o...
Autores principales: | , , |
---|---|
Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961080/ https://www.ncbi.nlm.nih.gov/pubmed/21202196 http://dx.doi.org/10.1107/S1600536808009471 |
_version_ | 1782188896655769600 |
---|---|
author | Song, Wen-Dong Fan, Run-Zhen Wu, Hong-Mian |
author_facet | Song, Wen-Dong Fan, Run-Zhen Wu, Hong-Mian |
author_sort | Song, Wen-Dong |
collection | PubMed |
description | In the mononuclear title compound, [Ni(C(8)H(7)O(2))(2)(C(3)H(4)N(2))(2)(H(2)O)], the Ni(II) atom is coordinated by three carboxylate O atoms (from a bidentate 4-methylbenzoate ligand and a monodentate 4-methylbenzoate ligand), two N atoms (from two imidazole ligands) and a water molecule in an octahedral geometry. Intermolecular O—H⋯O hydrogen-bonding interactions lead to infinite chains, which are further self-assembled into a supramolecular network through intermolecular N—H⋯O hydrogen-bonding interactions and π–π stacking [centroid–centroid distance = 3.717 (2) Å]. |
format | Text |
id | pubmed-2961080 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29610802010-12-30 Aquabis(1H-imidazole-κN (3))bis(4-methylbenzoato)-κO;κO,O′-nickel(II) Song, Wen-Dong Fan, Run-Zhen Wu, Hong-Mian Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the mononuclear title compound, [Ni(C(8)H(7)O(2))(2)(C(3)H(4)N(2))(2)(H(2)O)], the Ni(II) atom is coordinated by three carboxylate O atoms (from a bidentate 4-methylbenzoate ligand and a monodentate 4-methylbenzoate ligand), two N atoms (from two imidazole ligands) and a water molecule in an octahedral geometry. Intermolecular O—H⋯O hydrogen-bonding interactions lead to infinite chains, which are further self-assembled into a supramolecular network through intermolecular N—H⋯O hydrogen-bonding interactions and π–π stacking [centroid–centroid distance = 3.717 (2) Å]. International Union of Crystallography 2008-04-10 /pmc/articles/PMC2961080/ /pubmed/21202196 http://dx.doi.org/10.1107/S1600536808009471 Text en © Song et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Song, Wen-Dong Fan, Run-Zhen Wu, Hong-Mian Aquabis(1H-imidazole-κN (3))bis(4-methylbenzoato)-κO;κO,O′-nickel(II) |
title | Aquabis(1H-imidazole-κN
(3))bis(4-methylbenzoato)-κO;κO,O′-nickel(II) |
title_full | Aquabis(1H-imidazole-κN
(3))bis(4-methylbenzoato)-κO;κO,O′-nickel(II) |
title_fullStr | Aquabis(1H-imidazole-κN
(3))bis(4-methylbenzoato)-κO;κO,O′-nickel(II) |
title_full_unstemmed | Aquabis(1H-imidazole-κN
(3))bis(4-methylbenzoato)-κO;κO,O′-nickel(II) |
title_short | Aquabis(1H-imidazole-κN
(3))bis(4-methylbenzoato)-κO;κO,O′-nickel(II) |
title_sort | aquabis(1h-imidazole-κn
(3))bis(4-methylbenzoato)-κo;κo,o′-nickel(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961080/ https://www.ncbi.nlm.nih.gov/pubmed/21202196 http://dx.doi.org/10.1107/S1600536808009471 |
work_keys_str_mv | AT songwendong aquabis1himidazolekn3bis4methylbenzoatokokoonickelii AT fanrunzhen aquabis1himidazolekn3bis4methylbenzoatokokoonickelii AT wuhongmian aquabis1himidazolekn3bis4methylbenzoatokokoonickelii |