Diaqua­bis(2,5-di-4-pyridyl-1,3,4-thia­diazole-κN (2))bis­(thio­cyanato-κN)copper(II) dihydrate

In the title compound, [Cu(NCS)(2)(C(12)H(8)N(4)S)(2)(H(2)O)(2)]·2H(2)O, the Cu atom is located on an inversion center and displays an octa­hedral geometry. Two N atoms of two different 2,5-di-4-pyridyl-1,3,4-thia­diazole ligands and two N atoms from two separate thio­cyanate mol­ecules form the equ...

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Detalles Bibliográficos
Autores principales: Ma, Wei-Wu, Yang, Ming-Hua
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961085/
https://www.ncbi.nlm.nih.gov/pubmed/21202184
http://dx.doi.org/10.1107/S1600536808008854
Descripción
Sumario:In the title compound, [Cu(NCS)(2)(C(12)H(8)N(4)S)(2)(H(2)O)(2)]·2H(2)O, the Cu atom is located on an inversion center and displays an octa­hedral geometry. Two N atoms of two different 2,5-di-4-pyridyl-1,3,4-thia­diazole ligands and two N atoms from two separate thio­cyanate mol­ecules form the equatorial plane, while two coordinated water mol­ecules are in axial positions. The crystal structure is consolidated by extensive hydrogen bonding, forming a two-dimensional network.

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