Bis{4-[(Z)-(4-fluoro­benzyl­amino)(phenyl)­methyl­ene]-3-methyl-1-phenyl-1H-pyrazol-5(4H)-onato-κ(2) N (4),O}nickel(II)

The mol­ecule of the title compound, [Ni(C(24)H(19)FN(3)O)(2)], has twofold rotation symmetry. The Ni(II) ion is in a square-planar coordination geometry which is distorted towards tetra­hedral and is coordinated by two N atoms of imine and two O atoms of pyrazolone from two Schiff base 4-[(Z)-(4-fl...

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Detalles Bibliográficos
Autores principales: Zhang, Xin, Zhang, Guo-Ying, Chen, Dan, Song, Yu-Jing
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961089/
https://www.ncbi.nlm.nih.gov/pubmed/21202192
http://dx.doi.org/10.1107/S1600536808009197
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author Zhang, Xin
Zhang, Guo-Ying
Chen, Dan
Song, Yu-Jing
author_facet Zhang, Xin
Zhang, Guo-Ying
Chen, Dan
Song, Yu-Jing
author_sort Zhang, Xin
collection PubMed
description The mol­ecule of the title compound, [Ni(C(24)H(19)FN(3)O)(2)], has twofold rotation symmetry. The Ni(II) ion is in a square-planar coordination geometry which is distorted towards tetra­hedral and is coordinated by two N atoms of imine and two O atoms of pyrazolone from two Schiff base 4-[(Z)-(4-fluoro­benzyl­amino)phenyl­methyl­ene]-3-methyl-1-phenyl-1H-pyrazol-5(4H)-onate ligands.
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spelling pubmed-29610892010-12-30 Bis{4-[(Z)-(4-fluoro­benzyl­amino)(phenyl)­methyl­ene]-3-methyl-1-phenyl-1H-pyrazol-5(4H)-onato-κ(2) N (4),O}nickel(II) Zhang, Xin Zhang, Guo-Ying Chen, Dan Song, Yu-Jing Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The mol­ecule of the title compound, [Ni(C(24)H(19)FN(3)O)(2)], has twofold rotation symmetry. The Ni(II) ion is in a square-planar coordination geometry which is distorted towards tetra­hedral and is coordinated by two N atoms of imine and two O atoms of pyrazolone from two Schiff base 4-[(Z)-(4-fluoro­benzyl­amino)phenyl­methyl­ene]-3-methyl-1-phenyl-1H-pyrazol-5(4H)-onate ligands. International Union of Crystallography 2008-04-10 /pmc/articles/PMC2961089/ /pubmed/21202192 http://dx.doi.org/10.1107/S1600536808009197 Text en © Zhang et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhang, Xin
Zhang, Guo-Ying
Chen, Dan
Song, Yu-Jing
Bis{4-[(Z)-(4-fluoro­benzyl­amino)(phenyl)­methyl­ene]-3-methyl-1-phenyl-1H-pyrazol-5(4H)-onato-κ(2) N (4),O}nickel(II)
title Bis{4-[(Z)-(4-fluoro­benzyl­amino)(phenyl)­methyl­ene]-3-methyl-1-phenyl-1H-pyrazol-5(4H)-onato-κ(2) N (4),O}nickel(II)
title_full Bis{4-[(Z)-(4-fluoro­benzyl­amino)(phenyl)­methyl­ene]-3-methyl-1-phenyl-1H-pyrazol-5(4H)-onato-κ(2) N (4),O}nickel(II)
title_fullStr Bis{4-[(Z)-(4-fluoro­benzyl­amino)(phenyl)­methyl­ene]-3-methyl-1-phenyl-1H-pyrazol-5(4H)-onato-κ(2) N (4),O}nickel(II)
title_full_unstemmed Bis{4-[(Z)-(4-fluoro­benzyl­amino)(phenyl)­methyl­ene]-3-methyl-1-phenyl-1H-pyrazol-5(4H)-onato-κ(2) N (4),O}nickel(II)
title_short Bis{4-[(Z)-(4-fluoro­benzyl­amino)(phenyl)­methyl­ene]-3-methyl-1-phenyl-1H-pyrazol-5(4H)-onato-κ(2) N (4),O}nickel(II)
title_sort bis{4-[(z)-(4-fluoro­benzyl­amino)(phenyl)­methyl­ene]-3-methyl-1-phenyl-1h-pyrazol-5(4h)-onato-κ(2) n (4),o}nickel(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961089/
https://www.ncbi.nlm.nih.gov/pubmed/21202192
http://dx.doi.org/10.1107/S1600536808009197
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