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{2-[(3,5-Dichloro-2-oxidobenzyl­idene)amino-κ(2) N,O]-3-methyl­penta­noato-κO}(N,N′-dimethyl­formamide-κO)copper(II)

In the title compound, [Cu(C(13)H(13)Cl(2)NO(3))(C(3)H(7)NO)], the Cu(II) atom is coordinated in a slightly distorted square-planar geometry by two O atoms and one N atom from the tridentate chiral ligand 2-[(3,5-dichloro-2-oxidobenzyl­idene)amino]-3-methyl­penta­noate and by one O atom from dimethy...

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Detalles Bibliográficos
Autores principales: Xia, Jin Hong, Liu, Zheng, Wang, Yuan, Feng, Xiao Zhen
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961092/
https://www.ncbi.nlm.nih.gov/pubmed/21202205
http://dx.doi.org/10.1107/S160053680800932X
Descripción
Sumario:In the title compound, [Cu(C(13)H(13)Cl(2)NO(3))(C(3)H(7)NO)], the Cu(II) atom is coordinated in a slightly distorted square-planar geometry by two O atoms and one N atom from the tridentate chiral ligand 2-[(3,5-dichloro-2-oxidobenzyl­idene)amino]-3-methyl­penta­noate and by one O atom from dimethyl­formamide. In the crystal structure, the Cu atom forms contacts with Cl and O atoms of two units (Cu⋯Cl and Cu⋯O = 3.401 and 2.947 Å, respectively), thereby forming an approximately octa­hedral arrangement. A three-dimensional network is constructed through Cl⋯Cu, O⋯Cu, Cl⋯Cl contacts and C—H⋯O hydrogen bonds.