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{2-[(3,5-Dichloro-2-oxidobenzyl­idene)amino-κ(2) N,O]-3-methyl­penta­noato-κO}(N,N′-dimethyl­formamide-κO)copper(II)

In the title compound, [Cu(C(13)H(13)Cl(2)NO(3))(C(3)H(7)NO)], the Cu(II) atom is coordinated in a slightly distorted square-planar geometry by two O atoms and one N atom from the tridentate chiral ligand 2-[(3,5-dichloro-2-oxidobenzyl­idene)amino]-3-methyl­penta­noate and by one O atom from dimethy...

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Detalles Bibliográficos
Autores principales: Xia, Jin Hong, Liu, Zheng, Wang, Yuan, Feng, Xiao Zhen
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961092/
https://www.ncbi.nlm.nih.gov/pubmed/21202205
http://dx.doi.org/10.1107/S160053680800932X
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author Xia, Jin Hong
Liu, Zheng
Wang, Yuan
Feng, Xiao Zhen
author_facet Xia, Jin Hong
Liu, Zheng
Wang, Yuan
Feng, Xiao Zhen
author_sort Xia, Jin Hong
collection PubMed
description In the title compound, [Cu(C(13)H(13)Cl(2)NO(3))(C(3)H(7)NO)], the Cu(II) atom is coordinated in a slightly distorted square-planar geometry by two O atoms and one N atom from the tridentate chiral ligand 2-[(3,5-dichloro-2-oxidobenzyl­idene)amino]-3-methyl­penta­noate and by one O atom from dimethyl­formamide. In the crystal structure, the Cu atom forms contacts with Cl and O atoms of two units (Cu⋯Cl and Cu⋯O = 3.401 and 2.947 Å, respectively), thereby forming an approximately octa­hedral arrangement. A three-dimensional network is constructed through Cl⋯Cu, O⋯Cu, Cl⋯Cl contacts and C—H⋯O hydrogen bonds.
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spelling pubmed-29610922010-12-30 {2-[(3,5-Dichloro-2-oxidobenzyl­idene)amino-κ(2) N,O]-3-methyl­penta­noato-κO}(N,N′-dimethyl­formamide-κO)copper(II) Xia, Jin Hong Liu, Zheng Wang, Yuan Feng, Xiao Zhen Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cu(C(13)H(13)Cl(2)NO(3))(C(3)H(7)NO)], the Cu(II) atom is coordinated in a slightly distorted square-planar geometry by two O atoms and one N atom from the tridentate chiral ligand 2-[(3,5-dichloro-2-oxidobenzyl­idene)amino]-3-methyl­penta­noate and by one O atom from dimethyl­formamide. In the crystal structure, the Cu atom forms contacts with Cl and O atoms of two units (Cu⋯Cl and Cu⋯O = 3.401 and 2.947 Å, respectively), thereby forming an approximately octa­hedral arrangement. A three-dimensional network is constructed through Cl⋯Cu, O⋯Cu, Cl⋯Cl contacts and C—H⋯O hydrogen bonds. International Union of Crystallography 2008-04-16 /pmc/articles/PMC2961092/ /pubmed/21202205 http://dx.doi.org/10.1107/S160053680800932X Text en © Xia et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Xia, Jin Hong
Liu, Zheng
Wang, Yuan
Feng, Xiao Zhen
{2-[(3,5-Dichloro-2-oxidobenzyl­idene)amino-κ(2) N,O]-3-methyl­penta­noato-κO}(N,N′-dimethyl­formamide-κO)copper(II)
title {2-[(3,5-Dichloro-2-oxidobenzyl­idene)amino-κ(2) N,O]-3-methyl­penta­noato-κO}(N,N′-dimethyl­formamide-κO)copper(II)
title_full {2-[(3,5-Dichloro-2-oxidobenzyl­idene)amino-κ(2) N,O]-3-methyl­penta­noato-κO}(N,N′-dimethyl­formamide-κO)copper(II)
title_fullStr {2-[(3,5-Dichloro-2-oxidobenzyl­idene)amino-κ(2) N,O]-3-methyl­penta­noato-κO}(N,N′-dimethyl­formamide-κO)copper(II)
title_full_unstemmed {2-[(3,5-Dichloro-2-oxidobenzyl­idene)amino-κ(2) N,O]-3-methyl­penta­noato-κO}(N,N′-dimethyl­formamide-κO)copper(II)
title_short {2-[(3,5-Dichloro-2-oxidobenzyl­idene)amino-κ(2) N,O]-3-methyl­penta­noato-κO}(N,N′-dimethyl­formamide-κO)copper(II)
title_sort {2-[(3,5-dichloro-2-oxidobenzyl­idene)amino-κ(2) n,o]-3-methyl­penta­noato-κo}(n,n′-dimethyl­formamide-κo)copper(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961092/
https://www.ncbi.nlm.nih.gov/pubmed/21202205
http://dx.doi.org/10.1107/S160053680800932X
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