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{2-[(3,5-Dichloro-2-oxidobenzylidene)amino-κ(2) N,O]-3-methylpentanoato-κO}(N,N′-dimethylformamide-κO)copper(II)
In the title compound, [Cu(C(13)H(13)Cl(2)NO(3))(C(3)H(7)NO)], the Cu(II) atom is coordinated in a slightly distorted square-planar geometry by two O atoms and one N atom from the tridentate chiral ligand 2-[(3,5-dichloro-2-oxidobenzylidene)amino]-3-methylpentanoate and by one O atom from dimethy...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961092/ https://www.ncbi.nlm.nih.gov/pubmed/21202205 http://dx.doi.org/10.1107/S160053680800932X |
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author | Xia, Jin Hong Liu, Zheng Wang, Yuan Feng, Xiao Zhen |
author_facet | Xia, Jin Hong Liu, Zheng Wang, Yuan Feng, Xiao Zhen |
author_sort | Xia, Jin Hong |
collection | PubMed |
description | In the title compound, [Cu(C(13)H(13)Cl(2)NO(3))(C(3)H(7)NO)], the Cu(II) atom is coordinated in a slightly distorted square-planar geometry by two O atoms and one N atom from the tridentate chiral ligand 2-[(3,5-dichloro-2-oxidobenzylidene)amino]-3-methylpentanoate and by one O atom from dimethylformamide. In the crystal structure, the Cu atom forms contacts with Cl and O atoms of two units (Cu⋯Cl and Cu⋯O = 3.401 and 2.947 Å, respectively), thereby forming an approximately octahedral arrangement. A three-dimensional network is constructed through Cl⋯Cu, O⋯Cu, Cl⋯Cl contacts and C—H⋯O hydrogen bonds. |
format | Text |
id | pubmed-2961092 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29610922010-12-30 {2-[(3,5-Dichloro-2-oxidobenzylidene)amino-κ(2) N,O]-3-methylpentanoato-κO}(N,N′-dimethylformamide-κO)copper(II) Xia, Jin Hong Liu, Zheng Wang, Yuan Feng, Xiao Zhen Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cu(C(13)H(13)Cl(2)NO(3))(C(3)H(7)NO)], the Cu(II) atom is coordinated in a slightly distorted square-planar geometry by two O atoms and one N atom from the tridentate chiral ligand 2-[(3,5-dichloro-2-oxidobenzylidene)amino]-3-methylpentanoate and by one O atom from dimethylformamide. In the crystal structure, the Cu atom forms contacts with Cl and O atoms of two units (Cu⋯Cl and Cu⋯O = 3.401 and 2.947 Å, respectively), thereby forming an approximately octahedral arrangement. A three-dimensional network is constructed through Cl⋯Cu, O⋯Cu, Cl⋯Cl contacts and C—H⋯O hydrogen bonds. International Union of Crystallography 2008-04-16 /pmc/articles/PMC2961092/ /pubmed/21202205 http://dx.doi.org/10.1107/S160053680800932X Text en © Xia et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Xia, Jin Hong Liu, Zheng Wang, Yuan Feng, Xiao Zhen {2-[(3,5-Dichloro-2-oxidobenzylidene)amino-κ(2) N,O]-3-methylpentanoato-κO}(N,N′-dimethylformamide-κO)copper(II) |
title | {2-[(3,5-Dichloro-2-oxidobenzylidene)amino-κ(2)
N,O]-3-methylpentanoato-κO}(N,N′-dimethylformamide-κO)copper(II) |
title_full | {2-[(3,5-Dichloro-2-oxidobenzylidene)amino-κ(2)
N,O]-3-methylpentanoato-κO}(N,N′-dimethylformamide-κO)copper(II) |
title_fullStr | {2-[(3,5-Dichloro-2-oxidobenzylidene)amino-κ(2)
N,O]-3-methylpentanoato-κO}(N,N′-dimethylformamide-κO)copper(II) |
title_full_unstemmed | {2-[(3,5-Dichloro-2-oxidobenzylidene)amino-κ(2)
N,O]-3-methylpentanoato-κO}(N,N′-dimethylformamide-κO)copper(II) |
title_short | {2-[(3,5-Dichloro-2-oxidobenzylidene)amino-κ(2)
N,O]-3-methylpentanoato-κO}(N,N′-dimethylformamide-κO)copper(II) |
title_sort | {2-[(3,5-dichloro-2-oxidobenzylidene)amino-κ(2)
n,o]-3-methylpentanoato-κo}(n,n′-dimethylformamide-κo)copper(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961092/ https://www.ncbi.nlm.nih.gov/pubmed/21202205 http://dx.doi.org/10.1107/S160053680800932X |
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