Bis(5-amino-4-amino­carbonyl-1H-imid­azol-3-ium) (5-amino-4-amino­carbonyl-1H-imidazol-3-ium-κO)-di-μ-chlorido-hepta­chlorido-dibismuth(III) mono­hydrate

The title compound, (C(4)H(7)N(4)O)(2)[Bi(2)Cl(9)(C(4)H(7)N(4)O)]·H(2)O, was prepared by the reaction of bis­muth trichloride and 5-amino-1H-imidazole-4-carboxamide in a dilute HCl medium. The asymmetric unit contains two 5-amino-4-amino­carbonyl-1H-imidazol-3-ium cations, one edge-shared non-centro...

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Autores principales: Lv, Lu-Ping, He, Lian-Jun, Li, Wei-Wei, Yu, Wen-Bo, Hu, Xian-Chao
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961098/
https://www.ncbi.nlm.nih.gov/pubmed/21202193
http://dx.doi.org/10.1107/S1600536808009367
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author Lv, Lu-Ping
He, Lian-Jun
Li, Wei-Wei
Yu, Wen-Bo
Hu, Xian-Chao
author_facet Lv, Lu-Ping
He, Lian-Jun
Li, Wei-Wei
Yu, Wen-Bo
Hu, Xian-Chao
author_sort Lv, Lu-Ping
collection PubMed
description The title compound, (C(4)H(7)N(4)O)(2)[Bi(2)Cl(9)(C(4)H(7)N(4)O)]·H(2)O, was prepared by the reaction of bis­muth trichloride and 5-amino-1H-imidazole-4-carboxamide in a dilute HCl medium. The asymmetric unit contains two 5-amino-4-amino­carbonyl-1H-imidazol-3-ium cations, one edge-shared non-centrosymmetric biocta­hedral [Bi(2)C1(9)(C(4)H(7)N(4)O)](2−) dianion and a water mol­ecule. In the dianion, the planar 5-amino-4-amino­carbonyl-1H-imidazol-3-ium ligand occupies an equatorial site and is inclined at an angle of 75.7 (2)° to the Bi(2)(μ-C1)(2) plane. The salt forms a three-dimensional network arising from hydrogen bonds between cations, anions and water mol­ecules.
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spelling pubmed-29610982010-12-30 Bis(5-amino-4-amino­carbonyl-1H-imid­azol-3-ium) (5-amino-4-amino­carbonyl-1H-imidazol-3-ium-κO)-di-μ-chlorido-hepta­chlorido-dibismuth(III) mono­hydrate Lv, Lu-Ping He, Lian-Jun Li, Wei-Wei Yu, Wen-Bo Hu, Xian-Chao Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, (C(4)H(7)N(4)O)(2)[Bi(2)Cl(9)(C(4)H(7)N(4)O)]·H(2)O, was prepared by the reaction of bis­muth trichloride and 5-amino-1H-imidazole-4-carboxamide in a dilute HCl medium. The asymmetric unit contains two 5-amino-4-amino­carbonyl-1H-imidazol-3-ium cations, one edge-shared non-centrosymmetric biocta­hedral [Bi(2)C1(9)(C(4)H(7)N(4)O)](2−) dianion and a water mol­ecule. In the dianion, the planar 5-amino-4-amino­carbonyl-1H-imidazol-3-ium ligand occupies an equatorial site and is inclined at an angle of 75.7 (2)° to the Bi(2)(μ-C1)(2) plane. The salt forms a three-dimensional network arising from hydrogen bonds between cations, anions and water mol­ecules. International Union of Crystallography 2008-04-10 /pmc/articles/PMC2961098/ /pubmed/21202193 http://dx.doi.org/10.1107/S1600536808009367 Text en © Lv et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Lv, Lu-Ping
He, Lian-Jun
Li, Wei-Wei
Yu, Wen-Bo
Hu, Xian-Chao
Bis(5-amino-4-amino­carbonyl-1H-imid­azol-3-ium) (5-amino-4-amino­carbonyl-1H-imidazol-3-ium-κO)-di-μ-chlorido-hepta­chlorido-dibismuth(III) mono­hydrate
title Bis(5-amino-4-amino­carbonyl-1H-imid­azol-3-ium) (5-amino-4-amino­carbonyl-1H-imidazol-3-ium-κO)-di-μ-chlorido-hepta­chlorido-dibismuth(III) mono­hydrate
title_full Bis(5-amino-4-amino­carbonyl-1H-imid­azol-3-ium) (5-amino-4-amino­carbonyl-1H-imidazol-3-ium-κO)-di-μ-chlorido-hepta­chlorido-dibismuth(III) mono­hydrate
title_fullStr Bis(5-amino-4-amino­carbonyl-1H-imid­azol-3-ium) (5-amino-4-amino­carbonyl-1H-imidazol-3-ium-κO)-di-μ-chlorido-hepta­chlorido-dibismuth(III) mono­hydrate
title_full_unstemmed Bis(5-amino-4-amino­carbonyl-1H-imid­azol-3-ium) (5-amino-4-amino­carbonyl-1H-imidazol-3-ium-κO)-di-μ-chlorido-hepta­chlorido-dibismuth(III) mono­hydrate
title_short Bis(5-amino-4-amino­carbonyl-1H-imid­azol-3-ium) (5-amino-4-amino­carbonyl-1H-imidazol-3-ium-κO)-di-μ-chlorido-hepta­chlorido-dibismuth(III) mono­hydrate
title_sort bis(5-amino-4-amino­carbonyl-1h-imid­azol-3-ium) (5-amino-4-amino­carbonyl-1h-imidazol-3-ium-κo)-di-μ-chlorido-hepta­chlorido-dibismuth(iii) mono­hydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961098/
https://www.ncbi.nlm.nih.gov/pubmed/21202193
http://dx.doi.org/10.1107/S1600536808009367
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AT yuwenbo bis5amino4aminocarbonyl1himidazol3ium5amino4aminocarbonyl1himidazol3iumkodimchloridoheptachloridodibismuthiiimonohydrate
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