Cargando…
5,6-Dichloro-2-(2-hydroxyphenyl)isoindoline-1,3-dione
In the molecule of the title compound, C(14)H(7)Cl(2)NO(3), the phthalimide ring system is virtually planar, with a dihedral angle between the fused five- and six-membered rings of 4.02 (3)°. In the crystal structure, intermolecular C—H⋯O and O—H⋯O hydrogen bonds and C—Cl⋯O close contacts [Cl⋯O =...
Autores principales: | , |
---|---|
Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961102/ https://www.ncbi.nlm.nih.gov/pubmed/21202271 http://dx.doi.org/10.1107/S1600536808008180 |
_version_ | 1782188901846220800 |
---|---|
author | Büyükgüngör, Orhan Odabaşoğlu, Mustafa |
author_facet | Büyükgüngör, Orhan Odabaşoğlu, Mustafa |
author_sort | Büyükgüngör, Orhan |
collection | PubMed |
description | In the molecule of the title compound, C(14)H(7)Cl(2)NO(3), the phthalimide ring system is virtually planar, with a dihedral angle between the fused five- and six-membered rings of 4.02 (3)°. In the crystal structure, intermolecular C—H⋯O and O—H⋯O hydrogen bonds and C—Cl⋯O close contacts [Cl⋯O = 3.0123 (13) Å and C—Cl⋯O = 171.14 (7)°] link the molecules, generating R (2) (2)(16), R (4) (2)(19) and R (4) (4)(22) ring motifs by C(6) chains to form a three-dimensional network. A weak π–π interaction between the six-membered rings of the phthalimide ring systems further stabilizes the structure, with a centroid–centroid distance of 3.666 (3) Å and an interplanar separation of 3.568 Å. |
format | Text |
id | pubmed-2961102 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29611022010-12-30 5,6-Dichloro-2-(2-hydroxyphenyl)isoindoline-1,3-dione Büyükgüngör, Orhan Odabaşoğlu, Mustafa Acta Crystallogr Sect E Struct Rep Online Organic Papers In the molecule of the title compound, C(14)H(7)Cl(2)NO(3), the phthalimide ring system is virtually planar, with a dihedral angle between the fused five- and six-membered rings of 4.02 (3)°. In the crystal structure, intermolecular C—H⋯O and O—H⋯O hydrogen bonds and C—Cl⋯O close contacts [Cl⋯O = 3.0123 (13) Å and C—Cl⋯O = 171.14 (7)°] link the molecules, generating R (2) (2)(16), R (4) (2)(19) and R (4) (4)(22) ring motifs by C(6) chains to form a three-dimensional network. A weak π–π interaction between the six-membered rings of the phthalimide ring systems further stabilizes the structure, with a centroid–centroid distance of 3.666 (3) Å and an interplanar separation of 3.568 Å. International Union of Crystallography 2008-04-02 /pmc/articles/PMC2961102/ /pubmed/21202271 http://dx.doi.org/10.1107/S1600536808008180 Text en © Büyükgüngör and Odabaşoğlu 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Büyükgüngör, Orhan Odabaşoğlu, Mustafa 5,6-Dichloro-2-(2-hydroxyphenyl)isoindoline-1,3-dione |
title | 5,6-Dichloro-2-(2-hydroxyphenyl)isoindoline-1,3-dione |
title_full | 5,6-Dichloro-2-(2-hydroxyphenyl)isoindoline-1,3-dione |
title_fullStr | 5,6-Dichloro-2-(2-hydroxyphenyl)isoindoline-1,3-dione |
title_full_unstemmed | 5,6-Dichloro-2-(2-hydroxyphenyl)isoindoline-1,3-dione |
title_short | 5,6-Dichloro-2-(2-hydroxyphenyl)isoindoline-1,3-dione |
title_sort | 5,6-dichloro-2-(2-hydroxyphenyl)isoindoline-1,3-dione |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961102/ https://www.ncbi.nlm.nih.gov/pubmed/21202271 http://dx.doi.org/10.1107/S1600536808008180 |
work_keys_str_mv | AT buyukgungororhan 56dichloro22hydroxyphenylisoindoline13dione AT odabasoglumustafa 56dichloro22hydroxyphenylisoindoline13dione |