Bis(2-bromo­pyridinium) hexa­chlorido­stannate(IV)

The asymmetric unit of the title compound, (C(5)H(5)BrN)(2)[SnCl(6)], contains one cation and one half-anion. The [SnCl(6)](2−) anion is located on an inversion center and forms a quasi-regular octa­hedral arrangement. Hydrogen-bonding inter­actions of two kinds, viz. N—H⋯Cl—Sn and C—H⋯Cl—Sn, along...

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Detalles Bibliográficos
Autores principales: Ali, Basem Fares, Al-Far, Rawhi, Haddad, Salim F.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961104/
https://www.ncbi.nlm.nih.gov/pubmed/21202188
http://dx.doi.org/10.1107/S160053680800901X
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author Ali, Basem Fares
Al-Far, Rawhi
Haddad, Salim F.
author_facet Ali, Basem Fares
Al-Far, Rawhi
Haddad, Salim F.
author_sort Ali, Basem Fares
collection PubMed
description The asymmetric unit of the title compound, (C(5)H(5)BrN)(2)[SnCl(6)], contains one cation and one half-anion. The [SnCl(6)](2−) anion is located on an inversion center and forms a quasi-regular octa­hedral arrangement. Hydrogen-bonding inter­actions of two kinds, viz. N—H⋯Cl—Sn and C—H⋯Cl—Sn, along with Cl⋯Br inter­actions [3.4393 (15) Å], connect the ions in the crystal structure into two-dimensional supra­molecular arrays. These supra­molecular arrays are arranged in layers approximately parallel to (110) built up from anions inter­acting with six symmetry-related surrounding cations.
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spelling pubmed-29611042010-12-30 Bis(2-bromo­pyridinium) hexa­chlorido­stannate(IV) Ali, Basem Fares Al-Far, Rawhi Haddad, Salim F. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, (C(5)H(5)BrN)(2)[SnCl(6)], contains one cation and one half-anion. The [SnCl(6)](2−) anion is located on an inversion center and forms a quasi-regular octa­hedral arrangement. Hydrogen-bonding inter­actions of two kinds, viz. N—H⋯Cl—Sn and C—H⋯Cl—Sn, along with Cl⋯Br inter­actions [3.4393 (15) Å], connect the ions in the crystal structure into two-dimensional supra­molecular arrays. These supra­molecular arrays are arranged in layers approximately parallel to (110) built up from anions inter­acting with six symmetry-related surrounding cations. International Union of Crystallography 2008-04-10 /pmc/articles/PMC2961104/ /pubmed/21202188 http://dx.doi.org/10.1107/S160053680800901X Text en © Ali et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Ali, Basem Fares
Al-Far, Rawhi
Haddad, Salim F.
Bis(2-bromo­pyridinium) hexa­chlorido­stannate(IV)
title Bis(2-bromo­pyridinium) hexa­chlorido­stannate(IV)
title_full Bis(2-bromo­pyridinium) hexa­chlorido­stannate(IV)
title_fullStr Bis(2-bromo­pyridinium) hexa­chlorido­stannate(IV)
title_full_unstemmed Bis(2-bromo­pyridinium) hexa­chlorido­stannate(IV)
title_short Bis(2-bromo­pyridinium) hexa­chlorido­stannate(IV)
title_sort bis(2-bromo­pyridinium) hexa­chlorido­stannate(iv)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961104/
https://www.ncbi.nlm.nih.gov/pubmed/21202188
http://dx.doi.org/10.1107/S160053680800901X
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AT alfarrawhi bis2bromopyridiniumhexachloridostannateiv
AT haddadsalimf bis2bromopyridiniumhexachloridostannateiv

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