catena-Poly[[[bis­[4-(1H-1,3,7,8-tetra­azacyclo­penta­[l]phenanthren-2-yl)phenol-κ(2) N (7),N (8)]manganese(II)]-μ-naphthalene-1,4-dicarboxyl­ato-κ(2) O (1):O (4)] naphthalene-1,4-dicarboxylic acid hemisolvate monohydrate]

The 1,4-dicarboxyl­ate dianions in the title compound, [Mn(C(12)H(6)O(4))(C(19)H(12)N(4)O)(2)]·0.5C(12)H(8)O(4)·H(2)O, bond to two 4-(1H-1,3,7,8-tetra­azacyclo­penta­[l]phenanthren-2-yl)phenol-chelated Mn atoms to form a chain that features the metal atom in an octa­hedral coordination geometry. Adj...

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Detalles Bibliográficos
Autores principales: Li, Heng-Da, Li, Xiu-Ying, Xu, Mao-Liang, Ng, Seik Weng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961106/
https://www.ncbi.nlm.nih.gov/pubmed/21202234
http://dx.doi.org/10.1107/S160053680801074X
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author Li, Heng-Da
Li, Xiu-Ying
Xu, Mao-Liang
Ng, Seik Weng
author_facet Li, Heng-Da
Li, Xiu-Ying
Xu, Mao-Liang
Ng, Seik Weng
author_sort Li, Heng-Da
collection PubMed
description The 1,4-dicarboxyl­ate dianions in the title compound, [Mn(C(12)H(6)O(4))(C(19)H(12)N(4)O)(2)]·0.5C(12)H(8)O(4)·H(2)O, bond to two 4-(1H-1,3,7,8-tetra­azacyclo­penta­[l]phenanthren-2-yl)phenol-chelated Mn atoms to form a chain that features the metal atom in an octa­hedral coordination geometry. Adjacent chains inter­act with the uncoordinated water mol­ecules to form a three-dimensional network. The naphthalene-1,4-dicarboxylic acid solvent mol­ecule, which is disordered about a centre of inversion, occupies the space within the network but is not bonded to the network. One NH group is disordered equally over two positions.
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spelling pubmed-29611062010-12-30 catena-Poly[[[bis­[4-(1H-1,3,7,8-tetra­azacyclo­penta­[l]phenanthren-2-yl)phenol-κ(2) N (7),N (8)]manganese(II)]-μ-naphthalene-1,4-dicarboxyl­ato-κ(2) O (1):O (4)] naphthalene-1,4-dicarboxylic acid hemisolvate monohydrate] Li, Heng-Da Li, Xiu-Ying Xu, Mao-Liang Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The 1,4-dicarboxyl­ate dianions in the title compound, [Mn(C(12)H(6)O(4))(C(19)H(12)N(4)O)(2)]·0.5C(12)H(8)O(4)·H(2)O, bond to two 4-(1H-1,3,7,8-tetra­azacyclo­penta­[l]phenanthren-2-yl)phenol-chelated Mn atoms to form a chain that features the metal atom in an octa­hedral coordination geometry. Adjacent chains inter­act with the uncoordinated water mol­ecules to form a three-dimensional network. The naphthalene-1,4-dicarboxylic acid solvent mol­ecule, which is disordered about a centre of inversion, occupies the space within the network but is not bonded to the network. One NH group is disordered equally over two positions. International Union of Crystallography 2008-04-23 /pmc/articles/PMC2961106/ /pubmed/21202234 http://dx.doi.org/10.1107/S160053680801074X Text en © Li et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Li, Heng-Da
Li, Xiu-Ying
Xu, Mao-Liang
Ng, Seik Weng
catena-Poly[[[bis­[4-(1H-1,3,7,8-tetra­azacyclo­penta­[l]phenanthren-2-yl)phenol-κ(2) N (7),N (8)]manganese(II)]-μ-naphthalene-1,4-dicarboxyl­ato-κ(2) O (1):O (4)] naphthalene-1,4-dicarboxylic acid hemisolvate monohydrate]
title catena-Poly[[[bis­[4-(1H-1,3,7,8-tetra­azacyclo­penta­[l]phenanthren-2-yl)phenol-κ(2) N (7),N (8)]manganese(II)]-μ-naphthalene-1,4-dicarboxyl­ato-κ(2) O (1):O (4)] naphthalene-1,4-dicarboxylic acid hemisolvate monohydrate]
title_full catena-Poly[[[bis­[4-(1H-1,3,7,8-tetra­azacyclo­penta­[l]phenanthren-2-yl)phenol-κ(2) N (7),N (8)]manganese(II)]-μ-naphthalene-1,4-dicarboxyl­ato-κ(2) O (1):O (4)] naphthalene-1,4-dicarboxylic acid hemisolvate monohydrate]
title_fullStr catena-Poly[[[bis­[4-(1H-1,3,7,8-tetra­azacyclo­penta­[l]phenanthren-2-yl)phenol-κ(2) N (7),N (8)]manganese(II)]-μ-naphthalene-1,4-dicarboxyl­ato-κ(2) O (1):O (4)] naphthalene-1,4-dicarboxylic acid hemisolvate monohydrate]
title_full_unstemmed catena-Poly[[[bis­[4-(1H-1,3,7,8-tetra­azacyclo­penta­[l]phenanthren-2-yl)phenol-κ(2) N (7),N (8)]manganese(II)]-μ-naphthalene-1,4-dicarboxyl­ato-κ(2) O (1):O (4)] naphthalene-1,4-dicarboxylic acid hemisolvate monohydrate]
title_short catena-Poly[[[bis­[4-(1H-1,3,7,8-tetra­azacyclo­penta­[l]phenanthren-2-yl)phenol-κ(2) N (7),N (8)]manganese(II)]-μ-naphthalene-1,4-dicarboxyl­ato-κ(2) O (1):O (4)] naphthalene-1,4-dicarboxylic acid hemisolvate monohydrate]
title_sort catena-poly[[[bis­[4-(1h-1,3,7,8-tetra­azacyclo­penta­[l]phenanthren-2-yl)phenol-κ(2) n (7),n (8)]manganese(ii)]-μ-naphthalene-1,4-dicarboxyl­ato-κ(2) o (1):o (4)] naphthalene-1,4-dicarboxylic acid hemisolvate monohydrate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961106/
https://www.ncbi.nlm.nih.gov/pubmed/21202234
http://dx.doi.org/10.1107/S160053680801074X
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