The cocrystal aqua­chlorido{6,6′-di-tert-butyl-2,2′-[1,2-phenyl­enebis(nitrilo­methyl­idyne)]diphenolato-κ(4) O,N,N′,O′}­manganese(III)–chlorido{6,6′-di-tert-butyl-2,2′-[1,2-phenyl­enebis(nitrilo­methyl­idyne)]diphenolato-κ(4) O,N,N′,O′}(methanol-κO)manganese(III) (1/1)

The asymmetric unit of the title complex, [Mn(C(28)H(30)N(2)O(2))Cl(H(2)O)][Mn(C(28)H(30)N(2)O(2))Cl(CH(3)OH)], contains two discrete Mn(III) complexes of a Schiff base ligand, with an N(2)O(2) donor set. Both Mn(III) centers are in a distorted octa­hedral geometry with the N(2)O(2) donor atoms of the tetra­dentate Schiff base dianion in the equatorial plane. The axial positions in the coordination environment of one Mn(III) complex are occupied by a chloride ion and a water mol­ecule, but a methanol mol­ecule replaces the water mol­ecule in the other complex. The coordinated water mol­ecule takes part in an O—H⋯Cl hydrogen bond between the two Mn(III) complexes. In the crystal structure, O—H⋯Cl hydrogen bonds link the mol­ecules into infinite one-dimensional chains along the [100] direction. The crystal structure is stabilized by O—H⋯Cl hydrogen bonds together with weak C—H⋯O and C—H⋯Cl inter­actions. A C—H⋯π inter­action is also observed in the crystal structure.