1,4,8,11-Tetra­kis(carboxy­meth­yl)-5,5,7,12,12,14-hexa­methyl-4,11-diaza-1,8-diazo­niacyclo­tetra­decane dichloride dihydrate

The title compound, C(24)H(46)N(4)O(8) (2+)·2Cl(−)·2H(2)O, was synthes­ized by the hydrolysis of tetra­ethyl 2,2′,2′′,2′′′-(5,5,7,12,12,14-hexa­methyl-1,4,8,11-tetra­azacyclo­tetra­decane-1,4,8,11-tetra­yl) tetra­acetate in hydro­chloric acid solution. The crystal structure of the title compound con...

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Detalles Bibliográficos
Autores principales: Wang, Shi-Fan, Liu, Hai-Qing, Yao, Xue-Mei, Yang, Kai, Li, Xiao-Hong
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961112/
https://www.ncbi.nlm.nih.gov/pubmed/21202369
http://dx.doi.org/10.1107/S1600536808010532
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author Wang, Shi-Fan
Liu, Hai-Qing
Yao, Xue-Mei
Yang, Kai
Li, Xiao-Hong
author_facet Wang, Shi-Fan
Liu, Hai-Qing
Yao, Xue-Mei
Yang, Kai
Li, Xiao-Hong
author_sort Wang, Shi-Fan
collection PubMed
description The title compound, C(24)H(46)N(4)O(8) (2+)·2Cl(−)·2H(2)O, was synthes­ized by the hydrolysis of tetra­ethyl 2,2′,2′′,2′′′-(5,5,7,12,12,14-hexa­methyl-1,4,8,11-tetra­azacyclo­tetra­decane-1,4,8,11-tetra­yl) tetra­acetate in hydro­chloric acid solution. The crystal structure of the title compound consists of a 14-membered C(10)N(4) centrosymmetric cationic macrocycle which inter­acts with the chloride ions and water mol­ecules of crystallization to give a three-dimensional hydrogen-bonded network.
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spelling pubmed-29611122010-12-30 1,4,8,11-Tetra­kis(carboxy­meth­yl)-5,5,7,12,12,14-hexa­methyl-4,11-diaza-1,8-diazo­niacyclo­tetra­decane dichloride dihydrate Wang, Shi-Fan Liu, Hai-Qing Yao, Xue-Mei Yang, Kai Li, Xiao-Hong Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(24)H(46)N(4)O(8) (2+)·2Cl(−)·2H(2)O, was synthes­ized by the hydrolysis of tetra­ethyl 2,2′,2′′,2′′′-(5,5,7,12,12,14-hexa­methyl-1,4,8,11-tetra­azacyclo­tetra­decane-1,4,8,11-tetra­yl) tetra­acetate in hydro­chloric acid solution. The crystal structure of the title compound consists of a 14-membered C(10)N(4) centrosymmetric cationic macrocycle which inter­acts with the chloride ions and water mol­ecules of crystallization to give a three-dimensional hydrogen-bonded network. International Union of Crystallography 2008-04-23 /pmc/articles/PMC2961112/ /pubmed/21202369 http://dx.doi.org/10.1107/S1600536808010532 Text en © Wang et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Wang, Shi-Fan
Liu, Hai-Qing
Yao, Xue-Mei
Yang, Kai
Li, Xiao-Hong
1,4,8,11-Tetra­kis(carboxy­meth­yl)-5,5,7,12,12,14-hexa­methyl-4,11-diaza-1,8-diazo­niacyclo­tetra­decane dichloride dihydrate
title 1,4,8,11-Tetra­kis(carboxy­meth­yl)-5,5,7,12,12,14-hexa­methyl-4,11-diaza-1,8-diazo­niacyclo­tetra­decane dichloride dihydrate
title_full 1,4,8,11-Tetra­kis(carboxy­meth­yl)-5,5,7,12,12,14-hexa­methyl-4,11-diaza-1,8-diazo­niacyclo­tetra­decane dichloride dihydrate
title_fullStr 1,4,8,11-Tetra­kis(carboxy­meth­yl)-5,5,7,12,12,14-hexa­methyl-4,11-diaza-1,8-diazo­niacyclo­tetra­decane dichloride dihydrate
title_full_unstemmed 1,4,8,11-Tetra­kis(carboxy­meth­yl)-5,5,7,12,12,14-hexa­methyl-4,11-diaza-1,8-diazo­niacyclo­tetra­decane dichloride dihydrate
title_short 1,4,8,11-Tetra­kis(carboxy­meth­yl)-5,5,7,12,12,14-hexa­methyl-4,11-diaza-1,8-diazo­niacyclo­tetra­decane dichloride dihydrate
title_sort 1,4,8,11-tetra­kis(carboxy­meth­yl)-5,5,7,12,12,14-hexa­methyl-4,11-diaza-1,8-diazo­niacyclo­tetra­decane dichloride dihydrate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961112/
https://www.ncbi.nlm.nih.gov/pubmed/21202369
http://dx.doi.org/10.1107/S1600536808010532
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