Dicyclo­hexyl­ammonium bis­(chloro­difluoro­acetato-κO)cyclo­hexyl­diphenyl­stannate(IV)

In the title mixed-organyl stannate, (C(12)H(24)N)[Sn(C(6)H(5))(2)(C(6)H(11))(CClF(2)O(2))(2)], there are two cations and two anions in the asymmetric unit. Each five-coordinate Sn atom shows trans-C(3)SnO(2) trigonal bipyramidal coordination. The four Sn—O distances are approximately equal in the t...

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Detalles Bibliográficos
Autores principales: Teo, Yin Yin, Lo, Kong Mun, Ng, Seik Weng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961113/
https://www.ncbi.nlm.nih.gov/pubmed/21202250
http://dx.doi.org/10.1107/S1600536808011057
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author Teo, Yin Yin
Lo, Kong Mun
Ng, Seik Weng
author_facet Teo, Yin Yin
Lo, Kong Mun
Ng, Seik Weng
author_sort Teo, Yin Yin
collection PubMed
description In the title mixed-organyl stannate, (C(12)H(24)N)[Sn(C(6)H(5))(2)(C(6)H(11))(CClF(2)O(2))(2)], there are two cations and two anions in the asymmetric unit. Each five-coordinate Sn atom shows trans-C(3)SnO(2) trigonal bipyramidal coordination. The four Sn—O distances are approximately equal in the two independent anions. Each ammonium cation serves as a hydrogen-bond donor to two stannates, the hydrogen-bonding inter­actions giving rise to linear hydrogen-bonded chains.
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spelling pubmed-29611132010-12-30 Dicyclo­hexyl­ammonium bis­(chloro­difluoro­acetato-κO)cyclo­hexyl­diphenyl­stannate(IV) Teo, Yin Yin Lo, Kong Mun Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title mixed-organyl stannate, (C(12)H(24)N)[Sn(C(6)H(5))(2)(C(6)H(11))(CClF(2)O(2))(2)], there are two cations and two anions in the asymmetric unit. Each five-coordinate Sn atom shows trans-C(3)SnO(2) trigonal bipyramidal coordination. The four Sn—O distances are approximately equal in the two independent anions. Each ammonium cation serves as a hydrogen-bond donor to two stannates, the hydrogen-bonding inter­actions giving rise to linear hydrogen-bonded chains. International Union of Crystallography 2008-04-26 /pmc/articles/PMC2961113/ /pubmed/21202250 http://dx.doi.org/10.1107/S1600536808011057 Text en © Teo et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Teo, Yin Yin
Lo, Kong Mun
Ng, Seik Weng
Dicyclo­hexyl­ammonium bis­(chloro­difluoro­acetato-κO)cyclo­hexyl­diphenyl­stannate(IV)
title Dicyclo­hexyl­ammonium bis­(chloro­difluoro­acetato-κO)cyclo­hexyl­diphenyl­stannate(IV)
title_full Dicyclo­hexyl­ammonium bis­(chloro­difluoro­acetato-κO)cyclo­hexyl­diphenyl­stannate(IV)
title_fullStr Dicyclo­hexyl­ammonium bis­(chloro­difluoro­acetato-κO)cyclo­hexyl­diphenyl­stannate(IV)
title_full_unstemmed Dicyclo­hexyl­ammonium bis­(chloro­difluoro­acetato-κO)cyclo­hexyl­diphenyl­stannate(IV)
title_short Dicyclo­hexyl­ammonium bis­(chloro­difluoro­acetato-κO)cyclo­hexyl­diphenyl­stannate(IV)
title_sort dicyclo­hexyl­ammonium bis­(chloro­difluoro­acetato-κo)cyclo­hexyl­diphenyl­stannate(iv)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961113/
https://www.ncbi.nlm.nih.gov/pubmed/21202250
http://dx.doi.org/10.1107/S1600536808011057
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AT lokongmun dicyclohexylammoniumbischlorodifluoroacetatokocyclohexyldiphenylstannateiv
AT ngseikweng dicyclohexylammoniumbischlorodifluoroacetatokocyclohexyldiphenylstannateiv

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