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Dichloridobis(5-m-tolyl-1,3,4-thia­diazol-2-ylamine-κN (3))zinc(II)

In the mol­ecule of the title compound, [ZnCl(2)(C(9)H(9)N(3)S)(2)], the Zn(II) atom is four-coordinated by two N atoms from two 5-m-tolyl-1,3,4-thia­diazol-2-ylamine ligands and two Cl anions in a distorted tetra­hedral geometry. Intra­molecular N—H⋯N, N—H⋯Cl and C—H⋯S hydrogen bonds result in the...

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Detalles Bibliográficos
Autores principales: Wang, Bin, Wan, Rong, Yin, Li-He, Han, Feng, Wang, Jin-Tang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961117/
https://www.ncbi.nlm.nih.gov/pubmed/21202227
http://dx.doi.org/10.1107/S160053680801057X
Descripción
Sumario:In the mol­ecule of the title compound, [ZnCl(2)(C(9)H(9)N(3)S)(2)], the Zn(II) atom is four-coordinated by two N atoms from two 5-m-tolyl-1,3,4-thia­diazol-2-ylamine ligands and two Cl anions in a distorted tetra­hedral geometry. Intra­molecular N—H⋯N, N—H⋯Cl and C—H⋯S hydrogen bonds result in the formation of one planar and one non-planar five-membered, one non-planar six-membered and one non-planar seven-membered ring. The six- and seven-membered rings have twist conformations, while the non-planar five-membered ring adopts an envelope conformation with the S atom displaced by 0.541 (3) Å from the plane of the other ring atoms. The planar five-membered ring is oriented at dihedral angles of 1.74 (3) and 1.08 (3)°, respectively, with respect to the adjacent aromatic and thia­diazole rings. In the crystal structure, inter­molecular N—H⋯Cl hydrogen bonds link the mol­ecules into a three-dimensional network.