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Dichloridobis(5-m-tolyl-1,3,4-thiadiazol-2-ylamine-κN (3))zinc(II)
In the molecule of the title compound, [ZnCl(2)(C(9)H(9)N(3)S)(2)], the Zn(II) atom is four-coordinated by two N atoms from two 5-m-tolyl-1,3,4-thiadiazol-2-ylamine ligands and two Cl anions in a distorted tetrahedral geometry. Intramolecular N—H⋯N, N—H⋯Cl and C—H⋯S hydrogen bonds result in the...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961117/ https://www.ncbi.nlm.nih.gov/pubmed/21202227 http://dx.doi.org/10.1107/S160053680801057X |
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author | Wang, Bin Wan, Rong Yin, Li-He Han, Feng Wang, Jin-Tang |
author_facet | Wang, Bin Wan, Rong Yin, Li-He Han, Feng Wang, Jin-Tang |
author_sort | Wang, Bin |
collection | PubMed |
description | In the molecule of the title compound, [ZnCl(2)(C(9)H(9)N(3)S)(2)], the Zn(II) atom is four-coordinated by two N atoms from two 5-m-tolyl-1,3,4-thiadiazol-2-ylamine ligands and two Cl anions in a distorted tetrahedral geometry. Intramolecular N—H⋯N, N—H⋯Cl and C—H⋯S hydrogen bonds result in the formation of one planar and one non-planar five-membered, one non-planar six-membered and one non-planar seven-membered ring. The six- and seven-membered rings have twist conformations, while the non-planar five-membered ring adopts an envelope conformation with the S atom displaced by 0.541 (3) Å from the plane of the other ring atoms. The planar five-membered ring is oriented at dihedral angles of 1.74 (3) and 1.08 (3)°, respectively, with respect to the adjacent aromatic and thiadiazole rings. In the crystal structure, intermolecular N—H⋯Cl hydrogen bonds link the molecules into a three-dimensional network. |
format | Text |
id | pubmed-2961117 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29611172010-12-30 Dichloridobis(5-m-tolyl-1,3,4-thiadiazol-2-ylamine-κN (3))zinc(II) Wang, Bin Wan, Rong Yin, Li-He Han, Feng Wang, Jin-Tang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the molecule of the title compound, [ZnCl(2)(C(9)H(9)N(3)S)(2)], the Zn(II) atom is four-coordinated by two N atoms from two 5-m-tolyl-1,3,4-thiadiazol-2-ylamine ligands and two Cl anions in a distorted tetrahedral geometry. Intramolecular N—H⋯N, N—H⋯Cl and C—H⋯S hydrogen bonds result in the formation of one planar and one non-planar five-membered, one non-planar six-membered and one non-planar seven-membered ring. The six- and seven-membered rings have twist conformations, while the non-planar five-membered ring adopts an envelope conformation with the S atom displaced by 0.541 (3) Å from the plane of the other ring atoms. The planar five-membered ring is oriented at dihedral angles of 1.74 (3) and 1.08 (3)°, respectively, with respect to the adjacent aromatic and thiadiazole rings. In the crystal structure, intermolecular N—H⋯Cl hydrogen bonds link the molecules into a three-dimensional network. International Union of Crystallography 2008-04-23 /pmc/articles/PMC2961117/ /pubmed/21202227 http://dx.doi.org/10.1107/S160053680801057X Text en © Wang et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Wang, Bin Wan, Rong Yin, Li-He Han, Feng Wang, Jin-Tang Dichloridobis(5-m-tolyl-1,3,4-thiadiazol-2-ylamine-κN (3))zinc(II) |
title | Dichloridobis(5-m-tolyl-1,3,4-thiadiazol-2-ylamine-κN
(3))zinc(II) |
title_full | Dichloridobis(5-m-tolyl-1,3,4-thiadiazol-2-ylamine-κN
(3))zinc(II) |
title_fullStr | Dichloridobis(5-m-tolyl-1,3,4-thiadiazol-2-ylamine-κN
(3))zinc(II) |
title_full_unstemmed | Dichloridobis(5-m-tolyl-1,3,4-thiadiazol-2-ylamine-κN
(3))zinc(II) |
title_short | Dichloridobis(5-m-tolyl-1,3,4-thiadiazol-2-ylamine-κN
(3))zinc(II) |
title_sort | dichloridobis(5-m-tolyl-1,3,4-thiadiazol-2-ylamine-κn
(3))zinc(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961117/ https://www.ncbi.nlm.nih.gov/pubmed/21202227 http://dx.doi.org/10.1107/S160053680801057X |
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