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Dichloridobis(5-m-tolyl-1,3,4-thia­diazol-2-ylamine-κN (3))zinc(II)

In the mol­ecule of the title compound, [ZnCl(2)(C(9)H(9)N(3)S)(2)], the Zn(II) atom is four-coordinated by two N atoms from two 5-m-tolyl-1,3,4-thia­diazol-2-ylamine ligands and two Cl anions in a distorted tetra­hedral geometry. Intra­molecular N—H⋯N, N—H⋯Cl and C—H⋯S hydrogen bonds result in the...

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Detalles Bibliográficos
Autores principales: Wang, Bin, Wan, Rong, Yin, Li-He, Han, Feng, Wang, Jin-Tang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961117/
https://www.ncbi.nlm.nih.gov/pubmed/21202227
http://dx.doi.org/10.1107/S160053680801057X
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author Wang, Bin
Wan, Rong
Yin, Li-He
Han, Feng
Wang, Jin-Tang
author_facet Wang, Bin
Wan, Rong
Yin, Li-He
Han, Feng
Wang, Jin-Tang
author_sort Wang, Bin
collection PubMed
description In the mol­ecule of the title compound, [ZnCl(2)(C(9)H(9)N(3)S)(2)], the Zn(II) atom is four-coordinated by two N atoms from two 5-m-tolyl-1,3,4-thia­diazol-2-ylamine ligands and two Cl anions in a distorted tetra­hedral geometry. Intra­molecular N—H⋯N, N—H⋯Cl and C—H⋯S hydrogen bonds result in the formation of one planar and one non-planar five-membered, one non-planar six-membered and one non-planar seven-membered ring. The six- and seven-membered rings have twist conformations, while the non-planar five-membered ring adopts an envelope conformation with the S atom displaced by 0.541 (3) Å from the plane of the other ring atoms. The planar five-membered ring is oriented at dihedral angles of 1.74 (3) and 1.08 (3)°, respectively, with respect to the adjacent aromatic and thia­diazole rings. In the crystal structure, inter­molecular N—H⋯Cl hydrogen bonds link the mol­ecules into a three-dimensional network.
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spelling pubmed-29611172010-12-30 Dichloridobis(5-m-tolyl-1,3,4-thia­diazol-2-ylamine-κN (3))zinc(II) Wang, Bin Wan, Rong Yin, Li-He Han, Feng Wang, Jin-Tang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the mol­ecule of the title compound, [ZnCl(2)(C(9)H(9)N(3)S)(2)], the Zn(II) atom is four-coordinated by two N atoms from two 5-m-tolyl-1,3,4-thia­diazol-2-ylamine ligands and two Cl anions in a distorted tetra­hedral geometry. Intra­molecular N—H⋯N, N—H⋯Cl and C—H⋯S hydrogen bonds result in the formation of one planar and one non-planar five-membered, one non-planar six-membered and one non-planar seven-membered ring. The six- and seven-membered rings have twist conformations, while the non-planar five-membered ring adopts an envelope conformation with the S atom displaced by 0.541 (3) Å from the plane of the other ring atoms. The planar five-membered ring is oriented at dihedral angles of 1.74 (3) and 1.08 (3)°, respectively, with respect to the adjacent aromatic and thia­diazole rings. In the crystal structure, inter­molecular N—H⋯Cl hydrogen bonds link the mol­ecules into a three-dimensional network. International Union of Crystallography 2008-04-23 /pmc/articles/PMC2961117/ /pubmed/21202227 http://dx.doi.org/10.1107/S160053680801057X Text en © Wang et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wang, Bin
Wan, Rong
Yin, Li-He
Han, Feng
Wang, Jin-Tang
Dichloridobis(5-m-tolyl-1,3,4-thia­diazol-2-ylamine-κN (3))zinc(II)
title Dichloridobis(5-m-tolyl-1,3,4-thia­diazol-2-ylamine-κN (3))zinc(II)
title_full Dichloridobis(5-m-tolyl-1,3,4-thia­diazol-2-ylamine-κN (3))zinc(II)
title_fullStr Dichloridobis(5-m-tolyl-1,3,4-thia­diazol-2-ylamine-κN (3))zinc(II)
title_full_unstemmed Dichloridobis(5-m-tolyl-1,3,4-thia­diazol-2-ylamine-κN (3))zinc(II)
title_short Dichloridobis(5-m-tolyl-1,3,4-thia­diazol-2-ylamine-κN (3))zinc(II)
title_sort dichloridobis(5-m-tolyl-1,3,4-thia­diazol-2-ylamine-κn (3))zinc(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961117/
https://www.ncbi.nlm.nih.gov/pubmed/21202227
http://dx.doi.org/10.1107/S160053680801057X
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