Aqua­chloridodimethyl­phenyltin(IV)–15-crown-5 (2/1)

The Sn(IV) atom in the title compound, 2[Sn(CH(3))(2)(C(6)H(5))Cl(H(2)O)]·C(10)H(20)O(5), exists in a trans-C(3)SnClO trigonal bipyramidal geometry in which the organo substituents occupy the equatorial sites. The coordinated water mol­ecule forms two hydrogen bonds to the 15-crown-5 mol­ecule, whic...

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Detalles Bibliográficos
Autores principales: Armaghan, Mahsa, Amini, Mostafa M., Azadmehr, Amirreza, Gao, Shan, Ng, Seik Weng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961118/
https://www.ncbi.nlm.nih.gov/pubmed/21202247
http://dx.doi.org/10.1107/S1600536808011070
Descripción
Sumario:The Sn(IV) atom in the title compound, 2[Sn(CH(3))(2)(C(6)H(5))Cl(H(2)O)]·C(10)H(20)O(5), exists in a trans-C(3)SnClO trigonal bipyramidal geometry in which the organo substituents occupy the equatorial sites. The coordinated water mol­ecule forms two hydrogen bonds to the 15-crown-5 mol­ecule, which is disordered about a center of inversion.

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