Zn(2)(TeO(3))Br(2)

Single crystals of dizinc tellurium dibromide trioxide, Zn(2)(TeO(3))Br(2), were synthesized via a transport reaction in sealed evacuated silica tubes. The compound has a layered crystal structure in which the building units are [ZnO(4)Br] distorted square pyramids, [ZnO(2)Br(2)] distorted tetra­hed...

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Detalles Bibliográficos
Autores principales: Zhang, Dong, Johnsson, Mats
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Inorganic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961122/
https://www.ncbi.nlm.nih.gov/pubmed/21202162
http://dx.doi.org/10.1107/S1600536808011252
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author Zhang, Dong
Johnsson, Mats
author_facet Zhang, Dong
Johnsson, Mats
author_sort Zhang, Dong
collection PubMed
description Single crystals of dizinc tellurium dibromide trioxide, Zn(2)(TeO(3))Br(2), were synthesized via a transport reaction in sealed evacuated silica tubes. The compound has a layered crystal structure in which the building units are [ZnO(4)Br] distorted square pyramids, [ZnO(2)Br(2)] distorted tetra­hedra, and [TeO(3) E] tetra­hedra (E being the 5s (2) lone pair of Te(4+)) joined through sharing of edges and corners to form layers of no net charge. Bromine atoms and tellurium lone pairs protrude from the surfaces of each layer towards adjacent layers. This new compound Zn(2)(TeO(3))Br(2) is isostructural with the synthetic compounds Zn(2)(TeO(3))Cl(2), CuZn(TeO(3))(2), Co(2)(TeO(3))Br(2) and the mineral sophiite, Zn(2)(SeO(3))Cl(2).
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spelling pubmed-29611222010-12-30 Zn(2)(TeO(3))Br(2) Zhang, Dong Johnsson, Mats Acta Crystallogr Sect E Struct Rep Online Inorganic Papers Single crystals of dizinc tellurium dibromide trioxide, Zn(2)(TeO(3))Br(2), were synthesized via a transport reaction in sealed evacuated silica tubes. The compound has a layered crystal structure in which the building units are [ZnO(4)Br] distorted square pyramids, [ZnO(2)Br(2)] distorted tetra­hedra, and [TeO(3) E] tetra­hedra (E being the 5s (2) lone pair of Te(4+)) joined through sharing of edges and corners to form layers of no net charge. Bromine atoms and tellurium lone pairs protrude from the surfaces of each layer towards adjacent layers. This new compound Zn(2)(TeO(3))Br(2) is isostructural with the synthetic compounds Zn(2)(TeO(3))Cl(2), CuZn(TeO(3))(2), Co(2)(TeO(3))Br(2) and the mineral sophiite, Zn(2)(SeO(3))Cl(2). International Union of Crystallography 2008-04-26 /pmc/articles/PMC2961122/ /pubmed/21202162 http://dx.doi.org/10.1107/S1600536808011252 Text en © Zhang and Johnsson 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Inorganic Papers
Zhang, Dong
Johnsson, Mats
Zn(2)(TeO(3))Br(2)
title Zn(2)(TeO(3))Br(2)
title_full Zn(2)(TeO(3))Br(2)
title_fullStr Zn(2)(TeO(3))Br(2)
title_full_unstemmed Zn(2)(TeO(3))Br(2)
title_short Zn(2)(TeO(3))Br(2)
title_sort zn(2)(teo(3))br(2)
topic Inorganic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961122/
https://www.ncbi.nlm.nih.gov/pubmed/21202162
http://dx.doi.org/10.1107/S1600536808011252
work_keys_str_mv AT zhangdong zn2teo3br2
AT johnssonmats zn2teo3br2

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