2-Fluoro­anilinium N-(2-fluoro­phenyl)oxamate

The crystal structure of the title salt, C(6)H(7)FN(+)·C(8)H(5)FNO(3) (−), exhibits intra­molecular N—H⋯O and C—H⋯O and inter­molecular N—H⋯O and N—H⋯F hydrogen-bond inter­actions, the intra­molecular hydrogen-bond inter­actions generating S(6) and S(5) ring motifs. The dihedral angles between the a...

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Detalles Bibliográficos
Autores principales: Büyükgüngör, Orhan, Odabaşoğlu, Mustafa
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961128/
https://www.ncbi.nlm.nih.gov/pubmed/21202299
http://dx.doi.org/10.1107/S1600536808008891
Descripción
Sumario:The crystal structure of the title salt, C(6)H(7)FN(+)·C(8)H(5)FNO(3) (−), exhibits intra­molecular N—H⋯O and C—H⋯O and inter­molecular N—H⋯O and N—H⋯F hydrogen-bond inter­actions, the intra­molecular hydrogen-bond inter­actions generating S(6) and S(5) ring motifs. The dihedral angles between the aromatic ring and the intra­molecular hydrogen-bonded rings in the anion are 2.97 (7) and 6.70 (5)°. The two aromatic rings of the title compound are oriented with a dihedral angle of 77.25 (9)°.

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