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(3,5-Dichloro­salicylaldehyde thio­semi­carbazonato-κ(3) S,N (1),O)(N,N′-dimethyl­formamide-κO)copper(II) dimethyl­formamide solvate

In the title compound, [Cu(C(8)H(5)Cl(2)N(3)OS)(C(3)H(7)NO)]·C(3)H(7)NO, the Cu(II) atom is coordinated in a slightly distorted square-planar geometry by an O, an S and an N atom from the tridentate ligand 3,5-dichloro­salicylaldehyde thio­semi­carb­azonate ligand and one O atom from dimethyl­formam...

Descripción completa

Detalles Bibliográficos
Autores principales: Wang, Yuan, Liu, Zheng, Gao, Jiong-Yang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961129/
https://www.ncbi.nlm.nih.gov/pubmed/21202186
http://dx.doi.org/10.1107/S1600536808008982
Descripción
Sumario:In the title compound, [Cu(C(8)H(5)Cl(2)N(3)OS)(C(3)H(7)NO)]·C(3)H(7)NO, the Cu(II) atom is coordinated in a slightly distorted square-planar geometry by an O, an S and an N atom from the tridentate ligand 3,5-dichloro­salicylaldehyde thio­semi­carb­azonate ligand and one O atom from dimethyl­formamide. At the same time, the Cu atom is in contact with S and Cl atoms from another two complexes [Cu⋯S and Cu⋯Cl = 2.9791 (2) and 3.3800 (3) Å, respectively], thereby forming a [4 + 2] coordination geometry. The crystal structure exhibits N—H⋯O and N—H⋯N hydrogen bonds.