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(3,5-Dichlorosalicylaldehyde thiosemicarbazonato-κ(3) S,N (1),O)(N,N′-dimethylformamide-κO)copper(II) dimethylformamide solvate
In the title compound, [Cu(C(8)H(5)Cl(2)N(3)OS)(C(3)H(7)NO)]·C(3)H(7)NO, the Cu(II) atom is coordinated in a slightly distorted square-planar geometry by an O, an S and an N atom from the tridentate ligand 3,5-dichlorosalicylaldehyde thiosemicarbazonate ligand and one O atom from dimethylformam...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961129/ https://www.ncbi.nlm.nih.gov/pubmed/21202186 http://dx.doi.org/10.1107/S1600536808008982 |
Sumario: | In the title compound, [Cu(C(8)H(5)Cl(2)N(3)OS)(C(3)H(7)NO)]·C(3)H(7)NO, the Cu(II) atom is coordinated in a slightly distorted square-planar geometry by an O, an S and an N atom from the tridentate ligand 3,5-dichlorosalicylaldehyde thiosemicarbazonate ligand and one O atom from dimethylformamide. At the same time, the Cu atom is in contact with S and Cl atoms from another two complexes [Cu⋯S and Cu⋯Cl = 2.9791 (2) and 3.3800 (3) Å, respectively], thereby forming a [4 + 2] coordination geometry. The crystal structure exhibits N—H⋯O and N—H⋯N hydrogen bonds. |
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