(3,5-Dichloro­salicylaldehyde thio­semi­carbazonato-κ(3) S,N (1),O)(N,N′-dimethyl­formamide-κO)copper(II) dimethyl­formamide solvate

In the title compound, [Cu(C(8)H(5)Cl(2)N(3)OS)(C(3)H(7)NO)]·C(3)H(7)NO, the Cu(II) atom is coordinated in a slightly distorted square-planar geometry by an O, an S and an N atom from the tridentate ligand 3,5-dichloro­salicylaldehyde thio­semi­carb­azonate ligand and one O atom from dimethyl­formam...

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Detalles Bibliográficos
Autores principales: Wang, Yuan, Liu, Zheng, Gao, Jiong-Yang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961129/
https://www.ncbi.nlm.nih.gov/pubmed/21202186
http://dx.doi.org/10.1107/S1600536808008982
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author Wang, Yuan
Liu, Zheng
Gao, Jiong-Yang
author_facet Wang, Yuan
Liu, Zheng
Gao, Jiong-Yang
author_sort Wang, Yuan
collection PubMed
description In the title compound, [Cu(C(8)H(5)Cl(2)N(3)OS)(C(3)H(7)NO)]·C(3)H(7)NO, the Cu(II) atom is coordinated in a slightly distorted square-planar geometry by an O, an S and an N atom from the tridentate ligand 3,5-dichloro­salicylaldehyde thio­semi­carb­azonate ligand and one O atom from dimethyl­formamide. At the same time, the Cu atom is in contact with S and Cl atoms from another two complexes [Cu⋯S and Cu⋯Cl = 2.9791 (2) and 3.3800 (3) Å, respectively], thereby forming a [4 + 2] coordination geometry. The crystal structure exhibits N—H⋯O and N—H⋯N hydrogen bonds.
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spelling pubmed-29611292010-12-30 (3,5-Dichloro­salicylaldehyde thio­semi­carbazonato-κ(3) S,N (1),O)(N,N′-dimethyl­formamide-κO)copper(II) dimethyl­formamide solvate Wang, Yuan Liu, Zheng Gao, Jiong-Yang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cu(C(8)H(5)Cl(2)N(3)OS)(C(3)H(7)NO)]·C(3)H(7)NO, the Cu(II) atom is coordinated in a slightly distorted square-planar geometry by an O, an S and an N atom from the tridentate ligand 3,5-dichloro­salicylaldehyde thio­semi­carb­azonate ligand and one O atom from dimethyl­formamide. At the same time, the Cu atom is in contact with S and Cl atoms from another two complexes [Cu⋯S and Cu⋯Cl = 2.9791 (2) and 3.3800 (3) Å, respectively], thereby forming a [4 + 2] coordination geometry. The crystal structure exhibits N—H⋯O and N—H⋯N hydrogen bonds. International Union of Crystallography 2008-04-10 /pmc/articles/PMC2961129/ /pubmed/21202186 http://dx.doi.org/10.1107/S1600536808008982 Text en © Wang et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wang, Yuan
Liu, Zheng
Gao, Jiong-Yang
(3,5-Dichloro­salicylaldehyde thio­semi­carbazonato-κ(3) S,N (1),O)(N,N′-dimethyl­formamide-κO)copper(II) dimethyl­formamide solvate
title (3,5-Dichloro­salicylaldehyde thio­semi­carbazonato-κ(3) S,N (1),O)(N,N′-dimethyl­formamide-κO)copper(II) dimethyl­formamide solvate
title_full (3,5-Dichloro­salicylaldehyde thio­semi­carbazonato-κ(3) S,N (1),O)(N,N′-dimethyl­formamide-κO)copper(II) dimethyl­formamide solvate
title_fullStr (3,5-Dichloro­salicylaldehyde thio­semi­carbazonato-κ(3) S,N (1),O)(N,N′-dimethyl­formamide-κO)copper(II) dimethyl­formamide solvate
title_full_unstemmed (3,5-Dichloro­salicylaldehyde thio­semi­carbazonato-κ(3) S,N (1),O)(N,N′-dimethyl­formamide-κO)copper(II) dimethyl­formamide solvate
title_short (3,5-Dichloro­salicylaldehyde thio­semi­carbazonato-κ(3) S,N (1),O)(N,N′-dimethyl­formamide-κO)copper(II) dimethyl­formamide solvate
title_sort (3,5-dichloro­salicylaldehyde thio­semi­carbazonato-κ(3) s,n (1),o)(n,n′-dimethyl­formamide-κo)copper(ii) dimethyl­formamide solvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961129/
https://www.ncbi.nlm.nih.gov/pubmed/21202186
http://dx.doi.org/10.1107/S1600536808008982
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AT liuzheng 35dichlorosalicylaldehydethiosemicarbazonatok3sn1onndimethylformamidekocopperiidimethylformamidesolvate
AT gaojiongyang 35dichlorosalicylaldehydethiosemicarbazonatok3sn1onndimethylformamidekocopperiidimethylformamidesolvate

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