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(E)-2-[4-(Dimethyl­amino)styr­yl]-1-methyl­quinolinium iodide sesquihydrate

In the title compound, C(20)H(21)N(2) (+.)I(−)·1.5H(2)O, the cation exists in the E configuration and is not planar. The dihedral angle between the quinolinium and dimethyl­amino­phenyl rings is 9.26 (6)°. The O atom of one of the solvent water mol­ecules lies on a twofold rotation axis. In the crys...

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Detalles Bibliográficos
Autores principales: Chantrapromma, Suchada, Kobkeatthawin, Thawanrat, Chanawanno, Kullapa, Karalai, Chatchanok, Fun, Hoong-Kun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961130/
https://www.ncbi.nlm.nih.gov/pubmed/21202361
http://dx.doi.org/10.1107/S1600536808010465
Descripción
Sumario:In the title compound, C(20)H(21)N(2) (+.)I(−)·1.5H(2)O, the cation exists in the E configuration and is not planar. The dihedral angle between the quinolinium and dimethyl­amino­phenyl rings is 9.26 (6)°. The O atom of one of the solvent water mol­ecules lies on a twofold rotation axis. In the crystal structure, the cations form one-dimensional zigzag chains along the [001] direction. The cations are linked to water mol­ecules and iodide ions through weak C—H⋯O and C—H⋯I inter­actions, respectively. Water mol­ecules and iodide ions form O—H⋯O and O—H⋯I hydrogen bonds, which stabilize the crystal structure. A C—H⋯π inter­action is also present.