(E)-2-[4-(Dimethyl­amino)styr­yl]-1-methyl­quinolinium iodide sesquihydrate

In the title compound, C(20)H(21)N(2) (+.)I(−)·1.5H(2)O, the cation exists in the E configuration and is not planar. The dihedral angle between the quinolinium and dimethyl­amino­phenyl rings is 9.26 (6)°. The O atom of one of the solvent water mol­ecules lies on a twofold rotation axis. In the crys...

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Detalles Bibliográficos
Autores principales: Chantrapromma, Suchada, Kobkeatthawin, Thawanrat, Chanawanno, Kullapa, Karalai, Chatchanok, Fun, Hoong-Kun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961130/
https://www.ncbi.nlm.nih.gov/pubmed/21202361
http://dx.doi.org/10.1107/S1600536808010465
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author Chantrapromma, Suchada
Kobkeatthawin, Thawanrat
Chanawanno, Kullapa
Karalai, Chatchanok
Fun, Hoong-Kun
author_facet Chantrapromma, Suchada
Kobkeatthawin, Thawanrat
Chanawanno, Kullapa
Karalai, Chatchanok
Fun, Hoong-Kun
author_sort Chantrapromma, Suchada
collection PubMed
description In the title compound, C(20)H(21)N(2) (+.)I(−)·1.5H(2)O, the cation exists in the E configuration and is not planar. The dihedral angle between the quinolinium and dimethyl­amino­phenyl rings is 9.26 (6)°. The O atom of one of the solvent water mol­ecules lies on a twofold rotation axis. In the crystal structure, the cations form one-dimensional zigzag chains along the [001] direction. The cations are linked to water mol­ecules and iodide ions through weak C—H⋯O and C—H⋯I inter­actions, respectively. Water mol­ecules and iodide ions form O—H⋯O and O—H⋯I hydrogen bonds, which stabilize the crystal structure. A C—H⋯π inter­action is also present.
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spelling pubmed-29611302010-12-30 (E)-2-[4-(Dimethyl­amino)styr­yl]-1-methyl­quinolinium iodide sesquihydrate Chantrapromma, Suchada Kobkeatthawin, Thawanrat Chanawanno, Kullapa Karalai, Chatchanok Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(20)H(21)N(2) (+.)I(−)·1.5H(2)O, the cation exists in the E configuration and is not planar. The dihedral angle between the quinolinium and dimethyl­amino­phenyl rings is 9.26 (6)°. The O atom of one of the solvent water mol­ecules lies on a twofold rotation axis. In the crystal structure, the cations form one-dimensional zigzag chains along the [001] direction. The cations are linked to water mol­ecules and iodide ions through weak C—H⋯O and C—H⋯I inter­actions, respectively. Water mol­ecules and iodide ions form O—H⋯O and O—H⋯I hydrogen bonds, which stabilize the crystal structure. A C—H⋯π inter­action is also present. International Union of Crystallography 2008-04-18 /pmc/articles/PMC2961130/ /pubmed/21202361 http://dx.doi.org/10.1107/S1600536808010465 Text en © Chantrapromma et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Chantrapromma, Suchada
Kobkeatthawin, Thawanrat
Chanawanno, Kullapa
Karalai, Chatchanok
Fun, Hoong-Kun
(E)-2-[4-(Dimethyl­amino)styr­yl]-1-methyl­quinolinium iodide sesquihydrate
title (E)-2-[4-(Dimethyl­amino)styr­yl]-1-methyl­quinolinium iodide sesquihydrate
title_full (E)-2-[4-(Dimethyl­amino)styr­yl]-1-methyl­quinolinium iodide sesquihydrate
title_fullStr (E)-2-[4-(Dimethyl­amino)styr­yl]-1-methyl­quinolinium iodide sesquihydrate
title_full_unstemmed (E)-2-[4-(Dimethyl­amino)styr­yl]-1-methyl­quinolinium iodide sesquihydrate
title_short (E)-2-[4-(Dimethyl­amino)styr­yl]-1-methyl­quinolinium iodide sesquihydrate
title_sort (e)-2-[4-(dimethyl­amino)styr­yl]-1-methyl­quinolinium iodide sesquihydrate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961130/
https://www.ncbi.nlm.nih.gov/pubmed/21202361
http://dx.doi.org/10.1107/S1600536808010465
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AT chanawannokullapa e24dimethylaminostyryl1methylquinoliniumiodidesesquihydrate
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AT funhoongkun e24dimethylaminostyryl1methylquinoliniumiodidesesquihydrate

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