catena-Poly[[tetra­aqua­(μ-4,4′-bipyridine-κ(2) N:N′)zinc(II)] fumarate tetra­hydrate]

In the title compound, {[Zn(C(10)H(8)N(2))(H(2)O)(4)](C(4)H(2)O(4))·4H(2)O}(n), the Zn(II) atom is coordinated by two N atoms from two μ-4,4′-bipyridine ligands and four water mol­ecules in a distorted octa­hedral geometry. The coordination unit is extended through the Zn—N bond, leading to a one-di...

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Detalles Bibliográficos
Autores principales: Tian, Yong, Wu, Ya-Pan, Li, Dong-Sheng, Wang, Hui, Wang, Ji-Wu
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961133/
https://www.ncbi.nlm.nih.gov/pubmed/21202206
http://dx.doi.org/10.1107/S1600536808009227
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author Tian, Yong
Wu, Ya-Pan
Li, Dong-Sheng
Wang, Hui
Wang, Ji-Wu
author_facet Tian, Yong
Wu, Ya-Pan
Li, Dong-Sheng
Wang, Hui
Wang, Ji-Wu
author_sort Tian, Yong
collection PubMed
description In the title compound, {[Zn(C(10)H(8)N(2))(H(2)O)(4)](C(4)H(2)O(4))·4H(2)O}(n), the Zn(II) atom is coordinated by two N atoms from two μ-4,4′-bipyridine ligands and four water mol­ecules in a distorted octa­hedral geometry. The coordination unit is extended through the Zn—N bond, leading to a one-dimensional cationic chain. A twofold rotation axis passes through the Zn atom and along the axis of the 4,4′-bipyridine ligand. Each uncoordinated water mol­ecule acts as both hydrogen-bond donor and acceptor. A three-dimensional network is constructed through hydrogen bonds involving water mol­ecules and fumarate dianions.
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spelling pubmed-29611332010-12-30 catena-Poly[[tetra­aqua­(μ-4,4′-bipyridine-κ(2) N:N′)zinc(II)] fumarate tetra­hydrate] Tian, Yong Wu, Ya-Pan Li, Dong-Sheng Wang, Hui Wang, Ji-Wu Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, {[Zn(C(10)H(8)N(2))(H(2)O)(4)](C(4)H(2)O(4))·4H(2)O}(n), the Zn(II) atom is coordinated by two N atoms from two μ-4,4′-bipyridine ligands and four water mol­ecules in a distorted octa­hedral geometry. The coordination unit is extended through the Zn—N bond, leading to a one-dimensional cationic chain. A twofold rotation axis passes through the Zn atom and along the axis of the 4,4′-bipyridine ligand. Each uncoordinated water mol­ecule acts as both hydrogen-bond donor and acceptor. A three-dimensional network is constructed through hydrogen bonds involving water mol­ecules and fumarate dianions. International Union of Crystallography 2008-04-16 /pmc/articles/PMC2961133/ /pubmed/21202206 http://dx.doi.org/10.1107/S1600536808009227 Text en © Tian et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Tian, Yong
Wu, Ya-Pan
Li, Dong-Sheng
Wang, Hui
Wang, Ji-Wu
catena-Poly[[tetra­aqua­(μ-4,4′-bipyridine-κ(2) N:N′)zinc(II)] fumarate tetra­hydrate]
title catena-Poly[[tetra­aqua­(μ-4,4′-bipyridine-κ(2) N:N′)zinc(II)] fumarate tetra­hydrate]
title_full catena-Poly[[tetra­aqua­(μ-4,4′-bipyridine-κ(2) N:N′)zinc(II)] fumarate tetra­hydrate]
title_fullStr catena-Poly[[tetra­aqua­(μ-4,4′-bipyridine-κ(2) N:N′)zinc(II)] fumarate tetra­hydrate]
title_full_unstemmed catena-Poly[[tetra­aqua­(μ-4,4′-bipyridine-κ(2) N:N′)zinc(II)] fumarate tetra­hydrate]
title_short catena-Poly[[tetra­aqua­(μ-4,4′-bipyridine-κ(2) N:N′)zinc(II)] fumarate tetra­hydrate]
title_sort catena-poly[[tetra­aqua­(μ-4,4′-bipyridine-κ(2) n:n′)zinc(ii)] fumarate tetra­hydrate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961133/
https://www.ncbi.nlm.nih.gov/pubmed/21202206
http://dx.doi.org/10.1107/S1600536808009227
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AT wangjiwu catenapolytetraaquam44bipyridinek2nnzinciifumaratetetrahydrate

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