(Acetone-κO){6,6′-di-tert-butyl-2,2′-[1,2-phenyl­enebis(nitrilo­methyl­idyne)]diphenolato-κ(4) O,N,N′,O′}zinc(II)

The mol­ecule of the title compound, [Zn(C(28)H(30)N(2)O(2))(CH(3)COCH(3))], lies across a mirror plane with the Zn(II) ion and the acetone mol­ecule on the mirror plane. The Zn(II) ion is in a five-coordinate distorted square-pyramidal N(2)O(3) environment, with the two imine N and two phenolic O a...

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Detalles Bibliográficos
Autores principales: Eltayeb, Naser Eltaher, Teoh, Siang Guan, Chantrapromma, Suchada, Fun, Hoong-Kun, Adnan, Rohana
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961135/
https://www.ncbi.nlm.nih.gov/pubmed/21202259
http://dx.doi.org/10.1107/S1600536808011215
Descripción
Sumario:The mol­ecule of the title compound, [Zn(C(28)H(30)N(2)O(2))(CH(3)COCH(3))], lies across a mirror plane with the Zn(II) ion and the acetone mol­ecule on the mirror plane. The Zn(II) ion is in a five-coordinate distorted square-pyramidal N(2)O(3) environment, with the two imine N and two phenolic O atoms of the tetra­dentate Schiff base dianion in the basal plane and the acetone mol­ecule in the apical position. The central benzene ring makes a dihedral angle of 16.5 (2)° with the two outer phenolate rings. In the crystal structure, the mol­ecules are arranged into anti­parallel columns along the a axis.

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