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5-Iodo-2,7-dimethyl-3-phenyl­sulfonyl-1-benzofuran

The title compound, C(16)H(13)IO(3)S, was prepared by the oxidation of 5-iodo-2,7-dimethyl-3-phenyl­sulfanyl-1-benzofuran with 3-chloro­peroxy­benzoic acid. The phenyl ring makes a dihedral angle of 76.31 (8)° with the plane of the benzofuran fragment. The crystal structure is stabilized by aromatic...

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Detalles Bibliográficos
Autores principales: Choi, Hong Dae, Seo, Pil Ja, Son, Byeng Wha, Lee, Uk
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961136/
https://www.ncbi.nlm.nih.gov/pubmed/21202411
http://dx.doi.org/10.1107/S1600536808011240
Descripción
Sumario:The title compound, C(16)H(13)IO(3)S, was prepared by the oxidation of 5-iodo-2,7-dimethyl-3-phenyl­sulfanyl-1-benzofuran with 3-chloro­peroxy­benzoic acid. The phenyl ring makes a dihedral angle of 76.31 (8)° with the plane of the benzofuran fragment. The crystal structure is stabilized by aromatic π–π inter­actions between the furan and benzene rings of neighbouring mol­ecules, and between the benzene rings of neighbouring mol­ecules; the centroid–centroid distances within the stack are 3.700 (4) and 3.788 (4) Å. In addition, the crystal structure exhibits inter- and intra­molecular C—H⋯O inter­actions, and an I⋯O halogen bond with an I⋯O distance of 3.282 (2) Å and a nearly linear C—I⋯O angle of 165.69 (8)°.