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Bis(pyridine-κN)bis(triphenylphosphine-κP)copper(I) tetrafluoridoborate
The title compound, [Cu(C(5)H(5)N)(2)(C(18)H(15)P)(2)]BF(4), crystallizes as discrete [(PPh(3))(2)(py)(2)Cu](+) cations and [BF(4)](−) anions and is isostructural with the analogous perchlorate salt. The anion is located in close proximity to the pyridine ligands with weak C—H⋯F interactions appare...
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| Formato: | Texto |
| Lenguaje: | English |
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International Union of Crystallography
2008
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961139/ https://www.ncbi.nlm.nih.gov/pubmed/21202166 http://dx.doi.org/10.1107/S1600536808008386 |
| _version_ | 1782188910988754944 |
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| author | Healy, Peter C. |
| author_facet | Healy, Peter C. |
| author_sort | Healy, Peter C. |
| collection | PubMed |
| description | The title compound, [Cu(C(5)H(5)N)(2)(C(18)H(15)P)(2)]BF(4), crystallizes as discrete [(PPh(3))(2)(py)(2)Cu](+) cations and [BF(4)](−) anions and is isostructural with the analogous perchlorate salt. The anion is located in close proximity to the pyridine ligands with weak C—H⋯F interactions apparent. The P(2)CuN(2) coordination geometry is pseudo-tetrahedral, with P—Cu—P and N—Cu—N angles of 116.02 (6) and 101.5 (2)°, respectively. |
| format | Text |
| id | pubmed-2961139 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2008 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29611392010-12-30 Bis(pyridine-κN)bis(triphenylphosphine-κP)copper(I) tetrafluoridoborate Healy, Peter C. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Cu(C(5)H(5)N)(2)(C(18)H(15)P)(2)]BF(4), crystallizes as discrete [(PPh(3))(2)(py)(2)Cu](+) cations and [BF(4)](−) anions and is isostructural with the analogous perchlorate salt. The anion is located in close proximity to the pyridine ligands with weak C—H⋯F interactions apparent. The P(2)CuN(2) coordination geometry is pseudo-tetrahedral, with P—Cu—P and N—Cu—N angles of 116.02 (6) and 101.5 (2)°, respectively. International Union of Crystallography 2008-04-02 /pmc/articles/PMC2961139/ /pubmed/21202166 http://dx.doi.org/10.1107/S1600536808008386 Text en © Peter C. Healy 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Healy, Peter C. Bis(pyridine-κN)bis(triphenylphosphine-κP)copper(I) tetrafluoridoborate |
| title | Bis(pyridine-κN)bis(triphenylphosphine-κP)copper(I) tetrafluoridoborate |
| title_full | Bis(pyridine-κN)bis(triphenylphosphine-κP)copper(I) tetrafluoridoborate |
| title_fullStr | Bis(pyridine-κN)bis(triphenylphosphine-κP)copper(I) tetrafluoridoborate |
| title_full_unstemmed | Bis(pyridine-κN)bis(triphenylphosphine-κP)copper(I) tetrafluoridoborate |
| title_short | Bis(pyridine-κN)bis(triphenylphosphine-κP)copper(I) tetrafluoridoborate |
| title_sort | bis(pyridine-κn)bis(triphenylphosphine-κp)copper(i) tetrafluoridoborate |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961139/ https://www.ncbi.nlm.nih.gov/pubmed/21202166 http://dx.doi.org/10.1107/S1600536808008386 |
| work_keys_str_mv | AT healypeterc bispyridineknbistriphenylphosphinekpcopperitetrafluoridoborate |