2,2′-Diazinodimethylidyne)di-o-phenyl­ene) dibenzoate

The title compound, C(28)H(20)N(2)O(4), was synthesized by the reaction of 2-(hydrazonometh­yl)phenyl benzoate with iodine. The mol­ecule possesses a crystallographically imposed center of symmetry at the mid-point of the hydrazine N—N bond. The substituents at the ends of the C=N bonds adopt an E,E...

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Detalles Bibliográficos
Autores principales: Chattopadhyay, Basab, Basu, Sharmila, Ghosh, Somnath, Helliwell, Madeleine, Mukherjee, Monika
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961147/
https://www.ncbi.nlm.nih.gov/pubmed/21202353
http://dx.doi.org/10.1107/S1600536808010155
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author Chattopadhyay, Basab
Basu, Sharmila
Ghosh, Somnath
Helliwell, Madeleine
Mukherjee, Monika
author_facet Chattopadhyay, Basab
Basu, Sharmila
Ghosh, Somnath
Helliwell, Madeleine
Mukherjee, Monika
author_sort Chattopadhyay, Basab
collection PubMed
description The title compound, C(28)H(20)N(2)O(4), was synthesized by the reaction of 2-(hydrazonometh­yl)phenyl benzoate with iodine. The mol­ecule possesses a crystallographically imposed center of symmetry at the mid-point of the hydrazine N—N bond. The substituents at the ends of the C=N bonds adopt an E,E configuration. Inter­molecular C—H⋯π(arene) hydrogen bonds and aromatic π–π stacking inter­actions [centroid–centroid distance 3.900 (1) Å] link the mol­ecules into (100) sheets. In addition, there is an inter­molecular C—H⋯O hydrogen-bond inter­action.
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spelling pubmed-29611472010-12-30 2,2′-Diazinodimethylidyne)di-o-phenyl­ene) dibenzoate Chattopadhyay, Basab Basu, Sharmila Ghosh, Somnath Helliwell, Madeleine Mukherjee, Monika Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(28)H(20)N(2)O(4), was synthesized by the reaction of 2-(hydrazonometh­yl)phenyl benzoate with iodine. The mol­ecule possesses a crystallographically imposed center of symmetry at the mid-point of the hydrazine N—N bond. The substituents at the ends of the C=N bonds adopt an E,E configuration. Inter­molecular C—H⋯π(arene) hydrogen bonds and aromatic π–π stacking inter­actions [centroid–centroid distance 3.900 (1) Å] link the mol­ecules into (100) sheets. In addition, there is an inter­molecular C—H⋯O hydrogen-bond inter­action. International Union of Crystallography 2008-04-18 /pmc/articles/PMC2961147/ /pubmed/21202353 http://dx.doi.org/10.1107/S1600536808010155 Text en © Chattopadhyay et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Chattopadhyay, Basab
Basu, Sharmila
Ghosh, Somnath
Helliwell, Madeleine
Mukherjee, Monika
2,2′-Diazinodimethylidyne)di-o-phenyl­ene) dibenzoate
title 2,2′-Diazinodimethylidyne)di-o-phenyl­ene) dibenzoate
title_full 2,2′-Diazinodimethylidyne)di-o-phenyl­ene) dibenzoate
title_fullStr 2,2′-Diazinodimethylidyne)di-o-phenyl­ene) dibenzoate
title_full_unstemmed 2,2′-Diazinodimethylidyne)di-o-phenyl­ene) dibenzoate
title_short 2,2′-Diazinodimethylidyne)di-o-phenyl­ene) dibenzoate
title_sort 2,2′-diazinodimethylidyne)di-o-phenyl­ene) dibenzoate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961147/
https://www.ncbi.nlm.nih.gov/pubmed/21202353
http://dx.doi.org/10.1107/S1600536808010155
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