(2E)-3-(4-Chloro­phen­yl)-1-(1H-pyrrol-2-yl)prop-2-en-1-one

In the mol­ecule of the title compound, C(13)H(10)ClNO, the benzene and pyrrole rings are oriented at a dihedral angle of 7.37 (12)°. In the crystal structure, inter­molecular N—H⋯O hydrogen bonds link the mol­ecules into centrosymmetric R (2) (2)(10) dimers. There are C—H⋯π inter­actions between be...

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Autores principales: Bukhari, Mujahid Hussain, Siddiqui, Hamid Latif, Tahir, M. Nawaz, Chaudhary, Muhammad Ashraf, Iqbal, Amjid
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961151/
https://www.ncbi.nlm.nih.gov/pubmed/21202354
http://dx.doi.org/10.1107/S1600536808010362
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author Bukhari, Mujahid Hussain
Siddiqui, Hamid Latif
Tahir, M. Nawaz
Chaudhary, Muhammad Ashraf
Iqbal, Amjid
author_facet Bukhari, Mujahid Hussain
Siddiqui, Hamid Latif
Tahir, M. Nawaz
Chaudhary, Muhammad Ashraf
Iqbal, Amjid
author_sort Bukhari, Mujahid Hussain
collection PubMed
description In the mol­ecule of the title compound, C(13)H(10)ClNO, the benzene and pyrrole rings are oriented at a dihedral angle of 7.37 (12)°. In the crystal structure, inter­molecular N—H⋯O hydrogen bonds link the mol­ecules into centrosymmetric R (2) (2)(10) dimers. There are C—H⋯π inter­actions between benzene and pyrrole rings and a benzene C—H group. A weak π–π inter­action between the pyrrole rings [centroid–centroid distance 3.8515 (11) Å] further stabilizes the structure. There is also a π inter­action between the pyrrole ring and the carbonyl group, with a carbon–centroid distance of 3.4825 (18) Å.
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spelling pubmed-29611512010-12-30 (2E)-3-(4-Chloro­phen­yl)-1-(1H-pyrrol-2-yl)prop-2-en-1-one Bukhari, Mujahid Hussain Siddiqui, Hamid Latif Tahir, M. Nawaz Chaudhary, Muhammad Ashraf Iqbal, Amjid Acta Crystallogr Sect E Struct Rep Online Organic Papers In the mol­ecule of the title compound, C(13)H(10)ClNO, the benzene and pyrrole rings are oriented at a dihedral angle of 7.37 (12)°. In the crystal structure, inter­molecular N—H⋯O hydrogen bonds link the mol­ecules into centrosymmetric R (2) (2)(10) dimers. There are C—H⋯π inter­actions between benzene and pyrrole rings and a benzene C—H group. A weak π–π inter­action between the pyrrole rings [centroid–centroid distance 3.8515 (11) Å] further stabilizes the structure. There is also a π inter­action between the pyrrole ring and the carbonyl group, with a carbon–centroid distance of 3.4825 (18) Å. International Union of Crystallography 2008-04-18 /pmc/articles/PMC2961151/ /pubmed/21202354 http://dx.doi.org/10.1107/S1600536808010362 Text en © Bukhari et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Bukhari, Mujahid Hussain
Siddiqui, Hamid Latif
Tahir, M. Nawaz
Chaudhary, Muhammad Ashraf
Iqbal, Amjid
(2E)-3-(4-Chloro­phen­yl)-1-(1H-pyrrol-2-yl)prop-2-en-1-one
title (2E)-3-(4-Chloro­phen­yl)-1-(1H-pyrrol-2-yl)prop-2-en-1-one
title_full (2E)-3-(4-Chloro­phen­yl)-1-(1H-pyrrol-2-yl)prop-2-en-1-one
title_fullStr (2E)-3-(4-Chloro­phen­yl)-1-(1H-pyrrol-2-yl)prop-2-en-1-one
title_full_unstemmed (2E)-3-(4-Chloro­phen­yl)-1-(1H-pyrrol-2-yl)prop-2-en-1-one
title_short (2E)-3-(4-Chloro­phen­yl)-1-(1H-pyrrol-2-yl)prop-2-en-1-one
title_sort (2e)-3-(4-chloro­phen­yl)-1-(1h-pyrrol-2-yl)prop-2-en-1-one
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961151/
https://www.ncbi.nlm.nih.gov/pubmed/21202354
http://dx.doi.org/10.1107/S1600536808010362
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