catena-Poly[[[bis­[4-(1H-1,3,7,8-tetra­azacyclo­penta­[l]phenanthren-2-yl)­phenol-κ(2) N (7),N (8)]lead(II)]-μ-4,4′-oxy­dibenzoato-κ(3) O,O′:O′′] dihydrate]

The carboxyl­ate dianion in the title compound, [Pb(C(14)H(8)O(5))(C(19)H(12)N(4)O)(2)]·2H(2)O, uses one carboxyl­ate group to O,O′-chelate a bis­[4-(1H-1,3,7,8-tetra­azacyclo­penta­[l]phen­anthren-2-yl)phenol]-chelated Pb(II) atom and uses its other carboxyl­ate group to bind to another Pb(II) atom...

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Detalles Bibliográficos
Autores principales: Xu, Mao-Liang, Zhou, Rui, Wang, Ge-Yang, Ng, Seik Weng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961154/
https://www.ncbi.nlm.nih.gov/pubmed/21202241
http://dx.doi.org/10.1107/S1600536808010805
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author Xu, Mao-Liang
Zhou, Rui
Wang, Ge-Yang
Ng, Seik Weng
author_facet Xu, Mao-Liang
Zhou, Rui
Wang, Ge-Yang
Ng, Seik Weng
author_sort Xu, Mao-Liang
collection PubMed
description The carboxyl­ate dianion in the title compound, [Pb(C(14)H(8)O(5))(C(19)H(12)N(4)O)(2)]·2H(2)O, uses one carboxyl­ate group to O,O′-chelate a bis­[4-(1H-1,3,7,8-tetra­azacyclo­penta­[l]phen­anthren-2-yl)phenol]-chelated Pb(II) atom and uses its other carboxyl­ate group to bind to another Pb(II) atom in an irregular monodentate manner. The Pb(II) atom exists in an undefined seven-coordinate geometry in the chain structure; the lone pair is stereochemically active. Adjacent chains are linked by inter­molecular O—H⋯N, N—H⋯O and O—H⋯O hydrogen bonds that involve the uncoordinated water mol­ecules to form a three-dimensional network.
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spelling pubmed-29611542010-12-30 catena-Poly[[[bis­[4-(1H-1,3,7,8-tetra­azacyclo­penta­[l]phenanthren-2-yl)­phenol-κ(2) N (7),N (8)]lead(II)]-μ-4,4′-oxy­dibenzoato-κ(3) O,O′:O′′] dihydrate] Xu, Mao-Liang Zhou, Rui Wang, Ge-Yang Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The carboxyl­ate dianion in the title compound, [Pb(C(14)H(8)O(5))(C(19)H(12)N(4)O)(2)]·2H(2)O, uses one carboxyl­ate group to O,O′-chelate a bis­[4-(1H-1,3,7,8-tetra­azacyclo­penta­[l]phen­anthren-2-yl)phenol]-chelated Pb(II) atom and uses its other carboxyl­ate group to bind to another Pb(II) atom in an irregular monodentate manner. The Pb(II) atom exists in an undefined seven-coordinate geometry in the chain structure; the lone pair is stereochemically active. Adjacent chains are linked by inter­molecular O—H⋯N, N—H⋯O and O—H⋯O hydrogen bonds that involve the uncoordinated water mol­ecules to form a three-dimensional network. International Union of Crystallography 2008-04-23 /pmc/articles/PMC2961154/ /pubmed/21202241 http://dx.doi.org/10.1107/S1600536808010805 Text en © Xu et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Xu, Mao-Liang
Zhou, Rui
Wang, Ge-Yang
Ng, Seik Weng
catena-Poly[[[bis­[4-(1H-1,3,7,8-tetra­azacyclo­penta­[l]phenanthren-2-yl)­phenol-κ(2) N (7),N (8)]lead(II)]-μ-4,4′-oxy­dibenzoato-κ(3) O,O′:O′′] dihydrate]
title catena-Poly[[[bis­[4-(1H-1,3,7,8-tetra­azacyclo­penta­[l]phenanthren-2-yl)­phenol-κ(2) N (7),N (8)]lead(II)]-μ-4,4′-oxy­dibenzoato-κ(3) O,O′:O′′] dihydrate]
title_full catena-Poly[[[bis­[4-(1H-1,3,7,8-tetra­azacyclo­penta­[l]phenanthren-2-yl)­phenol-κ(2) N (7),N (8)]lead(II)]-μ-4,4′-oxy­dibenzoato-κ(3) O,O′:O′′] dihydrate]
title_fullStr catena-Poly[[[bis­[4-(1H-1,3,7,8-tetra­azacyclo­penta­[l]phenanthren-2-yl)­phenol-κ(2) N (7),N (8)]lead(II)]-μ-4,4′-oxy­dibenzoato-κ(3) O,O′:O′′] dihydrate]
title_full_unstemmed catena-Poly[[[bis­[4-(1H-1,3,7,8-tetra­azacyclo­penta­[l]phenanthren-2-yl)­phenol-κ(2) N (7),N (8)]lead(II)]-μ-4,4′-oxy­dibenzoato-κ(3) O,O′:O′′] dihydrate]
title_short catena-Poly[[[bis­[4-(1H-1,3,7,8-tetra­azacyclo­penta­[l]phenanthren-2-yl)­phenol-κ(2) N (7),N (8)]lead(II)]-μ-4,4′-oxy­dibenzoato-κ(3) O,O′:O′′] dihydrate]
title_sort catena-poly[[[bis­[4-(1h-1,3,7,8-tetra­azacyclo­penta­[l]phenanthren-2-yl)­phenol-κ(2) n (7),n (8)]lead(ii)]-μ-4,4′-oxy­dibenzoato-κ(3) o,o′:o′′] dihydrate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961154/
https://www.ncbi.nlm.nih.gov/pubmed/21202241
http://dx.doi.org/10.1107/S1600536808010805
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