Poly[bis­(μ(2)-benzyl­oxyacetato-κ(3) O,O′:O′′)cadmium(II)]

The title cadmium derivative of benzyl­oxyacetic acid, [Cd(C(9)H(9)O(3))(2)](n), exists as a μ (2)-carboxyl­ate-bridged layer network. Two benzyl­oxyacetate units each chelate the metal through a carboxylate as well as through the ether O atoms; the metal is also coordinated by the double-bond carbo...

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Detalles Bibliográficos
Autores principales: Liu, Ji-Wei, Ng, Seik Weng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961155/
https://www.ncbi.nlm.nih.gov/pubmed/21202238
http://dx.doi.org/10.1107/S1600536808010799
Descripción
Sumario:The title cadmium derivative of benzyl­oxyacetic acid, [Cd(C(9)H(9)O(3))(2)](n), exists as a μ (2)-carboxyl­ate-bridged layer network. Two benzyl­oxyacetate units each chelate the metal through a carboxylate as well as through the ether O atoms; the metal is also coordinated by the double-bond carbonyl O atom of two adjacent benzyl­oxyacetate units in an octa­hedral geometry. The metal atom lies on a special position of 2 site symmetry. The phenyl group is disordered equally over two positions.

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