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Poly[bis(μ(2)-benzyloxyacetato-κ(3) O,O′:O′′)cadmium(II)]
The title cadmium derivative of benzyloxyacetic acid, [Cd(C(9)H(9)O(3))(2)](n), exists as a μ (2)-carboxylate-bridged layer network. Two benzyloxyacetate units each chelate the metal through a carboxylate as well as through the ether O atoms; the metal is also coordinated by the double-bond carbo...
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| Formato: | Texto |
| Lenguaje: | English |
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International Union of Crystallography
2008
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961155/ https://www.ncbi.nlm.nih.gov/pubmed/21202238 http://dx.doi.org/10.1107/S1600536808010799 |
| _version_ | 1782188914923012096 |
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| author | Liu, Ji-Wei Ng, Seik Weng |
| author_facet | Liu, Ji-Wei Ng, Seik Weng |
| author_sort | Liu, Ji-Wei |
| collection | PubMed |
| description | The title cadmium derivative of benzyloxyacetic acid, [Cd(C(9)H(9)O(3))(2)](n), exists as a μ (2)-carboxylate-bridged layer network. Two benzyloxyacetate units each chelate the metal through a carboxylate as well as through the ether O atoms; the metal is also coordinated by the double-bond carbonyl O atom of two adjacent benzyloxyacetate units in an octahedral geometry. The metal atom lies on a special position of 2 site symmetry. The phenyl group is disordered equally over two positions. |
| format | Text |
| id | pubmed-2961155 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2008 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29611552010-12-30 Poly[bis(μ(2)-benzyloxyacetato-κ(3) O,O′:O′′)cadmium(II)] Liu, Ji-Wei Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title cadmium derivative of benzyloxyacetic acid, [Cd(C(9)H(9)O(3))(2)](n), exists as a μ (2)-carboxylate-bridged layer network. Two benzyloxyacetate units each chelate the metal through a carboxylate as well as through the ether O atoms; the metal is also coordinated by the double-bond carbonyl O atom of two adjacent benzyloxyacetate units in an octahedral geometry. The metal atom lies on a special position of 2 site symmetry. The phenyl group is disordered equally over two positions. International Union of Crystallography 2008-04-23 /pmc/articles/PMC2961155/ /pubmed/21202238 http://dx.doi.org/10.1107/S1600536808010799 Text en © Liu and Ng 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Liu, Ji-Wei Ng, Seik Weng Poly[bis(μ(2)-benzyloxyacetato-κ(3) O,O′:O′′)cadmium(II)] |
| title | Poly[bis(μ(2)-benzyloxyacetato-κ(3)
O,O′:O′′)cadmium(II)] |
| title_full | Poly[bis(μ(2)-benzyloxyacetato-κ(3)
O,O′:O′′)cadmium(II)] |
| title_fullStr | Poly[bis(μ(2)-benzyloxyacetato-κ(3)
O,O′:O′′)cadmium(II)] |
| title_full_unstemmed | Poly[bis(μ(2)-benzyloxyacetato-κ(3)
O,O′:O′′)cadmium(II)] |
| title_short | Poly[bis(μ(2)-benzyloxyacetato-κ(3)
O,O′:O′′)cadmium(II)] |
| title_sort | poly[bis(μ(2)-benzyloxyacetato-κ(3)
o,o′:o′′)cadmium(ii)] |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961155/ https://www.ncbi.nlm.nih.gov/pubmed/21202238 http://dx.doi.org/10.1107/S1600536808010799 |
| work_keys_str_mv | AT liujiwei polybism2benzyloxyacetatok3ooocadmiumii AT ngseikweng polybism2benzyloxyacetatok3ooocadmiumii |