Substitutional disorder in the substituted nixantphos ligand C(39)H(32)Br(0.27)Cl(0.73)NOP(2)

The structure of 10-(3-bromo/chloro­prop­yl)-4,6-bis­(diphenyl­phosphino)-10H-phenoxazine, C(39)H(32)Br(0.27)Cl(0.73)NOP(2), shows chloro/bromo substitutional disorder in a 3:1 ratio. For application as a ligand in catalysis, the intra­molecular P⋯P distance of 4.263 (2) Å is relevant. The phenoxazi...

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Detalles Bibliográficos
Autores principales: Marimuthu, Thashree, Bala, Muhammad D., Friedrich, Holger B.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961156/
https://www.ncbi.nlm.nih.gov/pubmed/21202266
http://dx.doi.org/10.1107/S1600536808007848
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author Marimuthu, Thashree
Bala, Muhammad D.
Friedrich, Holger B.
author_facet Marimuthu, Thashree
Bala, Muhammad D.
Friedrich, Holger B.
author_sort Marimuthu, Thashree
collection PubMed
description The structure of 10-(3-bromo/chloro­prop­yl)-4,6-bis­(diphenyl­phosphino)-10H-phenoxazine, C(39)H(32)Br(0.27)Cl(0.73)NOP(2), shows chloro/bromo substitutional disorder in a 3:1 ratio. For application as a ligand in catalysis, the intra­molecular P⋯P distance of 4.263 (2) Å is relevant. The phenoxazine ring system is essentially planar.
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spelling pubmed-29611562010-12-30 Substitutional disorder in the substituted nixantphos ligand C(39)H(32)Br(0.27)Cl(0.73)NOP(2) Marimuthu, Thashree Bala, Muhammad D. Friedrich, Holger B. Acta Crystallogr Sect E Struct Rep Online Organic Papers The structure of 10-(3-bromo/chloro­prop­yl)-4,6-bis­(diphenyl­phosphino)-10H-phenoxazine, C(39)H(32)Br(0.27)Cl(0.73)NOP(2), shows chloro/bromo substitutional disorder in a 3:1 ratio. For application as a ligand in catalysis, the intra­molecular P⋯P distance of 4.263 (2) Å is relevant. The phenoxazine ring system is essentially planar. International Union of Crystallography 2008-04-02 /pmc/articles/PMC2961156/ /pubmed/21202266 http://dx.doi.org/10.1107/S1600536808007848 Text en © Marimuthu et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Marimuthu, Thashree
Bala, Muhammad D.
Friedrich, Holger B.
Substitutional disorder in the substituted nixantphos ligand C(39)H(32)Br(0.27)Cl(0.73)NOP(2)
title Substitutional disorder in the substituted nixantphos ligand C(39)H(32)Br(0.27)Cl(0.73)NOP(2)
title_full Substitutional disorder in the substituted nixantphos ligand C(39)H(32)Br(0.27)Cl(0.73)NOP(2)
title_fullStr Substitutional disorder in the substituted nixantphos ligand C(39)H(32)Br(0.27)Cl(0.73)NOP(2)
title_full_unstemmed Substitutional disorder in the substituted nixantphos ligand C(39)H(32)Br(0.27)Cl(0.73)NOP(2)
title_short Substitutional disorder in the substituted nixantphos ligand C(39)H(32)Br(0.27)Cl(0.73)NOP(2)
title_sort substitutional disorder in the substituted nixantphos ligand c(39)h(32)br(0.27)cl(0.73)nop(2)
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961156/
https://www.ncbi.nlm.nih.gov/pubmed/21202266
http://dx.doi.org/10.1107/S1600536808007848
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