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Substitutional disorder in the substituted nixantphos ligand C(39)H(32)Br(0.27)Cl(0.73)NOP(2)

The structure of 10-(3-bromo/chloropropyl)-4,6-bis(diphenylphosphino)-10H-phenoxazine, C(39)H(32)Br(0.27)Cl(0.73)NOP(2), shows chloro/bromo substitutional disorder in a 3:1 ratio. For application as a ligand in catalysis, the intramolecular P⋯P distance of 4.263 (2) Å is relevant. The phenoxazi...

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Detalles Bibliográficos
Autores principales:	Marimuthu, Thashree, Bala, Muhammad D., Friedrich, Holger B.
Formato:	Texto
Lenguaje:	English
Publicado:	International Union of Crystallography 2008
Materias:	Organic Papers
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961156/ https://www.ncbi.nlm.nih.gov/pubmed/21202266 http://dx.doi.org/10.1107/S1600536808007848

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