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Dichloridobis(2-{1-[2-(1H-indol-3-yl)ethyliminio]ethyl}phenolate-κO)zinc(II)–2-{1-[2-(1H-indol-3-yl)ethyliminio]ethyl}phenolate (1/2)
In the mononuclear complex molecule of the title compond, [ZnCl(2)(C(18)H(18)N(2)O)(2)]·2C(18)H(18)N(2)O, the Zn atom, which lies on a twofold rotation axis, is coordinated by phenolate O atoms in a tetrahedral coordination geometry. The coordinated Schiff base uses its indole NH donor site to for...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961161/ https://www.ncbi.nlm.nih.gov/pubmed/21202245 http://dx.doi.org/10.1107/S1600536808011161 |
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author | Ali, Hapipah M. Mohamed Mustafa, Mohamed Ibrahim Rizal, Mohd. Razali Ng, Seik Weng |
author_facet | Ali, Hapipah M. Mohamed Mustafa, Mohamed Ibrahim Rizal, Mohd. Razali Ng, Seik Weng |
author_sort | Ali, Hapipah M. |
collection | PubMed |
description | In the mononuclear complex molecule of the title compond, [ZnCl(2)(C(18)H(18)N(2)O)(2)]·2C(18)H(18)N(2)O, the Zn atom, which lies on a twofold rotation axis, is coordinated by phenolate O atoms in a tetrahedral coordination geometry. The coordinated Schiff base uses its indole NH donor site to form a hydrogen bond to the negatively charged phenolate O atom of the uncoordinated zwitterionic Schiff base. There is an intramolecular N—H⋯O hydrogen bond in the coordinated and uncoordinated Schiff bases. The indole NH site of the uncoordinated Schiff base does not engage in a hydrogen-bond interaction. The CH(2)—CH(2) group in the uncoordinated Schiff base is disordered equally over two positions. |
format | Text |
id | pubmed-2961161 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29611612010-12-30 Dichloridobis(2-{1-[2-(1H-indol-3-yl)ethyliminio]ethyl}phenolate-κO)zinc(II)–2-{1-[2-(1H-indol-3-yl)ethyliminio]ethyl}phenolate (1/2) Ali, Hapipah M. Mohamed Mustafa, Mohamed Ibrahim Rizal, Mohd. Razali Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the mononuclear complex molecule of the title compond, [ZnCl(2)(C(18)H(18)N(2)O)(2)]·2C(18)H(18)N(2)O, the Zn atom, which lies on a twofold rotation axis, is coordinated by phenolate O atoms in a tetrahedral coordination geometry. The coordinated Schiff base uses its indole NH donor site to form a hydrogen bond to the negatively charged phenolate O atom of the uncoordinated zwitterionic Schiff base. There is an intramolecular N—H⋯O hydrogen bond in the coordinated and uncoordinated Schiff bases. The indole NH site of the uncoordinated Schiff base does not engage in a hydrogen-bond interaction. The CH(2)—CH(2) group in the uncoordinated Schiff base is disordered equally over two positions. International Union of Crystallography 2008-04-26 /pmc/articles/PMC2961161/ /pubmed/21202245 http://dx.doi.org/10.1107/S1600536808011161 Text en © Ali et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Ali, Hapipah M. Mohamed Mustafa, Mohamed Ibrahim Rizal, Mohd. Razali Ng, Seik Weng Dichloridobis(2-{1-[2-(1H-indol-3-yl)ethyliminio]ethyl}phenolate-κO)zinc(II)–2-{1-[2-(1H-indol-3-yl)ethyliminio]ethyl}phenolate (1/2) |
title | Dichloridobis(2-{1-[2-(1H-indol-3-yl)ethyliminio]ethyl}phenolate-κO)zinc(II)–2-{1-[2-(1H-indol-3-yl)ethyliminio]ethyl}phenolate (1/2) |
title_full | Dichloridobis(2-{1-[2-(1H-indol-3-yl)ethyliminio]ethyl}phenolate-κO)zinc(II)–2-{1-[2-(1H-indol-3-yl)ethyliminio]ethyl}phenolate (1/2) |
title_fullStr | Dichloridobis(2-{1-[2-(1H-indol-3-yl)ethyliminio]ethyl}phenolate-κO)zinc(II)–2-{1-[2-(1H-indol-3-yl)ethyliminio]ethyl}phenolate (1/2) |
title_full_unstemmed | Dichloridobis(2-{1-[2-(1H-indol-3-yl)ethyliminio]ethyl}phenolate-κO)zinc(II)–2-{1-[2-(1H-indol-3-yl)ethyliminio]ethyl}phenolate (1/2) |
title_short | Dichloridobis(2-{1-[2-(1H-indol-3-yl)ethyliminio]ethyl}phenolate-κO)zinc(II)–2-{1-[2-(1H-indol-3-yl)ethyliminio]ethyl}phenolate (1/2) |
title_sort | dichloridobis(2-{1-[2-(1h-indol-3-yl)ethyliminio]ethyl}phenolate-κo)zinc(ii)–2-{1-[2-(1h-indol-3-yl)ethyliminio]ethyl}phenolate (1/2) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961161/ https://www.ncbi.nlm.nih.gov/pubmed/21202245 http://dx.doi.org/10.1107/S1600536808011161 |
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