Cargando…

Dichloridobis(2-{1-[2-(1H-indol-3-yl)ethyl­iminio]eth­yl}phenolate-κO)zinc(II)–2-{1-[2-(1H-indol-3-yl)ethyl­iminio]eth­yl}phenolate (1/2)

In the mononuclear complex mol­ecule of the title compond, [ZnCl(2)(C(18)H(18)N(2)O)(2)]·2C(18)H(18)N(2)O, the Zn atom, which lies on a twofold rotation axis, is coordinated by phenolate O atoms in a tetra­hedral coordination geometry. The coordinated Schiff base uses its indole NH donor site to for...

Descripción completa

Detalles Bibliográficos
Autores principales: Ali, Hapipah M., Mohamed Mustafa, Mohamed Ibrahim, Rizal, Mohd. Razali, Ng, Seik Weng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961161/
https://www.ncbi.nlm.nih.gov/pubmed/21202245
http://dx.doi.org/10.1107/S1600536808011161
_version_ 1782188916318666752
author Ali, Hapipah M.
Mohamed Mustafa, Mohamed Ibrahim
Rizal, Mohd. Razali
Ng, Seik Weng
author_facet Ali, Hapipah M.
Mohamed Mustafa, Mohamed Ibrahim
Rizal, Mohd. Razali
Ng, Seik Weng
author_sort Ali, Hapipah M.
collection PubMed
description In the mononuclear complex mol­ecule of the title compond, [ZnCl(2)(C(18)H(18)N(2)O)(2)]·2C(18)H(18)N(2)O, the Zn atom, which lies on a twofold rotation axis, is coordinated by phenolate O atoms in a tetra­hedral coordination geometry. The coordinated Schiff base uses its indole NH donor site to form a hydrogen bond to the negatively charged phenolate O atom of the uncoordinated zwitterionic Schiff base. There is an intra­molecular N—H⋯O hydrogen bond in the coordinated and uncoordinated Schiff bases. The indole NH site of the uncoordinated Schiff base does not engage in a hydrogen-bond inter­action. The CH(2)—CH(2) group in the uncoordinated Schiff base is disordered equally over two positions.
format Text
id pubmed-2961161
institution National Center for Biotechnology Information
language English
publishDate 2008
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29611612010-12-30 Dichloridobis(2-{1-[2-(1H-indol-3-yl)ethyl­iminio]eth­yl}phenolate-κO)zinc(II)–2-{1-[2-(1H-indol-3-yl)ethyl­iminio]eth­yl}phenolate (1/2) Ali, Hapipah M. Mohamed Mustafa, Mohamed Ibrahim Rizal, Mohd. Razali Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the mononuclear complex mol­ecule of the title compond, [ZnCl(2)(C(18)H(18)N(2)O)(2)]·2C(18)H(18)N(2)O, the Zn atom, which lies on a twofold rotation axis, is coordinated by phenolate O atoms in a tetra­hedral coordination geometry. The coordinated Schiff base uses its indole NH donor site to form a hydrogen bond to the negatively charged phenolate O atom of the uncoordinated zwitterionic Schiff base. There is an intra­molecular N—H⋯O hydrogen bond in the coordinated and uncoordinated Schiff bases. The indole NH site of the uncoordinated Schiff base does not engage in a hydrogen-bond inter­action. The CH(2)—CH(2) group in the uncoordinated Schiff base is disordered equally over two positions. International Union of Crystallography 2008-04-26 /pmc/articles/PMC2961161/ /pubmed/21202245 http://dx.doi.org/10.1107/S1600536808011161 Text en © Ali et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Ali, Hapipah M.
Mohamed Mustafa, Mohamed Ibrahim
Rizal, Mohd. Razali
Ng, Seik Weng
Dichloridobis(2-{1-[2-(1H-indol-3-yl)ethyl­iminio]eth­yl}phenolate-κO)zinc(II)–2-{1-[2-(1H-indol-3-yl)ethyl­iminio]eth­yl}phenolate (1/2)
title Dichloridobis(2-{1-[2-(1H-indol-3-yl)ethyl­iminio]eth­yl}phenolate-κO)zinc(II)–2-{1-[2-(1H-indol-3-yl)ethyl­iminio]eth­yl}phenolate (1/2)
title_full Dichloridobis(2-{1-[2-(1H-indol-3-yl)ethyl­iminio]eth­yl}phenolate-κO)zinc(II)–2-{1-[2-(1H-indol-3-yl)ethyl­iminio]eth­yl}phenolate (1/2)
title_fullStr Dichloridobis(2-{1-[2-(1H-indol-3-yl)ethyl­iminio]eth­yl}phenolate-κO)zinc(II)–2-{1-[2-(1H-indol-3-yl)ethyl­iminio]eth­yl}phenolate (1/2)
title_full_unstemmed Dichloridobis(2-{1-[2-(1H-indol-3-yl)ethyl­iminio]eth­yl}phenolate-κO)zinc(II)–2-{1-[2-(1H-indol-3-yl)ethyl­iminio]eth­yl}phenolate (1/2)
title_short Dichloridobis(2-{1-[2-(1H-indol-3-yl)ethyl­iminio]eth­yl}phenolate-κO)zinc(II)–2-{1-[2-(1H-indol-3-yl)ethyl­iminio]eth­yl}phenolate (1/2)
title_sort dichloridobis(2-{1-[2-(1h-indol-3-yl)ethyl­iminio]eth­yl}phenolate-κo)zinc(ii)–2-{1-[2-(1h-indol-3-yl)ethyl­iminio]eth­yl}phenolate (1/2)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961161/
https://www.ncbi.nlm.nih.gov/pubmed/21202245
http://dx.doi.org/10.1107/S1600536808011161
work_keys_str_mv AT alihapipahm dichloridobis2121hindol3ylethyliminioethylphenolatekozincii2121hindol3ylethyliminioethylphenolate12
AT mohamedmustafamohamedibrahim dichloridobis2121hindol3ylethyliminioethylphenolatekozincii2121hindol3ylethyliminioethylphenolate12
AT rizalmohdrazali dichloridobis2121hindol3ylethyliminioethylphenolatekozincii2121hindol3ylethyliminioethylphenolate12
AT ngseikweng dichloridobis2121hindol3ylethyliminioethylphenolatekozincii2121hindol3ylethyliminioethylphenolate12