Bis[μ-bis­(diphenyl­phosphino)methane-κ(2) P:P′]bis­[(chloro­difluoro­acetato-κO)silver(I)](Ag—Ag)

The asymmetric unit of the title compound, [Ag(2)(C(2)ClF(2)O(2))(2)(C(25)H(22)P(2))(2)], consists of two half-mol­ecules, each Ag(I) ion lying on a center of symmetry. In each complete mol­ecule, two bis­(diphenyl­phosphino)methane ligands bridge two Ag(I) ions, which are further coordinated by one...

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Detalles Bibliográficos
Autores principales: Lo, Kong Mun, Ng, Seik Weng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961164/
https://www.ncbi.nlm.nih.gov/pubmed/21202244
http://dx.doi.org/10.1107/S1600536808011033
Descripción
Sumario:The asymmetric unit of the title compound, [Ag(2)(C(2)ClF(2)O(2))(2)(C(25)H(22)P(2))(2)], consists of two half-mol­ecules, each Ag(I) ion lying on a center of symmetry. In each complete mol­ecule, two bis­(diphenyl­phosphino)methane ligands bridge two Ag(I) ions, which are further coordinated by one chloro­difluoro­acetate ligand, giving T-shaped geometries and short intra­molecular Ag⋯Ag distances of 3.1078 (6) and 2.9950 (6) Å. In one mol­ecule, the unique –CF(2)Cl group is rotationally disordered over two sites with approximate occupancies of 0.53 and 0.47 for the major and minor components, respectively.

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