Bis[μ-bis­(diphenyl­phosphino)methane-κ(2) P:P′]bis­[(chloro­difluoro­acetato-κO)silver(I)](Ag—Ag)

The asymmetric unit of the title compound, [Ag(2)(C(2)ClF(2)O(2))(2)(C(25)H(22)P(2))(2)], consists of two half-mol­ecules, each Ag(I) ion lying on a center of symmetry. In each complete mol­ecule, two bis­(diphenyl­phosphino)methane ligands bridge two Ag(I) ions, which are further coordinated by one...

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Detalles Bibliográficos
Autores principales: Lo, Kong Mun, Ng, Seik Weng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961164/
https://www.ncbi.nlm.nih.gov/pubmed/21202244
http://dx.doi.org/10.1107/S1600536808011033
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author Lo, Kong Mun
Ng, Seik Weng
author_facet Lo, Kong Mun
Ng, Seik Weng
author_sort Lo, Kong Mun
collection PubMed
description The asymmetric unit of the title compound, [Ag(2)(C(2)ClF(2)O(2))(2)(C(25)H(22)P(2))(2)], consists of two half-mol­ecules, each Ag(I) ion lying on a center of symmetry. In each complete mol­ecule, two bis­(diphenyl­phosphino)methane ligands bridge two Ag(I) ions, which are further coordinated by one chloro­difluoro­acetate ligand, giving T-shaped geometries and short intra­molecular Ag⋯Ag distances of 3.1078 (6) and 2.9950 (6) Å. In one mol­ecule, the unique –CF(2)Cl group is rotationally disordered over two sites with approximate occupancies of 0.53 and 0.47 for the major and minor components, respectively.
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spelling pubmed-29611642010-12-30 Bis[μ-bis­(diphenyl­phosphino)methane-κ(2) P:P′]bis­[(chloro­difluoro­acetato-κO)silver(I)](Ag—Ag) Lo, Kong Mun Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, [Ag(2)(C(2)ClF(2)O(2))(2)(C(25)H(22)P(2))(2)], consists of two half-mol­ecules, each Ag(I) ion lying on a center of symmetry. In each complete mol­ecule, two bis­(diphenyl­phosphino)methane ligands bridge two Ag(I) ions, which are further coordinated by one chloro­difluoro­acetate ligand, giving T-shaped geometries and short intra­molecular Ag⋯Ag distances of 3.1078 (6) and 2.9950 (6) Å. In one mol­ecule, the unique –CF(2)Cl group is rotationally disordered over two sites with approximate occupancies of 0.53 and 0.47 for the major and minor components, respectively. International Union of Crystallography 2008-04-26 /pmc/articles/PMC2961164/ /pubmed/21202244 http://dx.doi.org/10.1107/S1600536808011033 Text en © Lo and Ng 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Lo, Kong Mun
Ng, Seik Weng
Bis[μ-bis­(diphenyl­phosphino)methane-κ(2) P:P′]bis­[(chloro­difluoro­acetato-κO)silver(I)](Ag—Ag)
title Bis[μ-bis­(diphenyl­phosphino)methane-κ(2) P:P′]bis­[(chloro­difluoro­acetato-κO)silver(I)](Ag—Ag)
title_full Bis[μ-bis­(diphenyl­phosphino)methane-κ(2) P:P′]bis­[(chloro­difluoro­acetato-κO)silver(I)](Ag—Ag)
title_fullStr Bis[μ-bis­(diphenyl­phosphino)methane-κ(2) P:P′]bis­[(chloro­difluoro­acetato-κO)silver(I)](Ag—Ag)
title_full_unstemmed Bis[μ-bis­(diphenyl­phosphino)methane-κ(2) P:P′]bis­[(chloro­difluoro­acetato-κO)silver(I)](Ag—Ag)
title_short Bis[μ-bis­(diphenyl­phosphino)methane-κ(2) P:P′]bis­[(chloro­difluoro­acetato-κO)silver(I)](Ag—Ag)
title_sort bis[μ-bis­(diphenyl­phosphino)methane-κ(2) p:p′]bis­[(chloro­difluoro­acetato-κo)silver(i)](ag—ag)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961164/
https://www.ncbi.nlm.nih.gov/pubmed/21202244
http://dx.doi.org/10.1107/S1600536808011033
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