Aqua­[N-(1-naphth­yl)acetamido-κN]bis­[2-(2-pyrid­yl)phenyl-κ(2) N,C (1)]iridium(III) ethyl­ene glycol hemisolvate

In the title compound, [Ir(C(11)H(8)N)(2)(C(12)H(10)NO)(H(2)O)]·0.5C(2)H(6)O(2), the iridium center is coordinated by two N atoms and two C atoms from two 2-(2-pyrid­yl)phenyl (ppy) ligands, one N atom from the N-(1-naphth­yl)acetamide ligand and one water O atom, forming a distorted octa­hedral env...

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Detalles Bibliográficos
Autores principales: Fu, Hao, Ding, Yuqiang, Chen, Guoqing
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961167/
https://www.ncbi.nlm.nih.gov/pubmed/21202254
http://dx.doi.org/10.1107/S1600536808010040
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author Fu, Hao
Ding, Yuqiang
Chen, Guoqing
author_facet Fu, Hao
Ding, Yuqiang
Chen, Guoqing
author_sort Fu, Hao
collection PubMed
description In the title compound, [Ir(C(11)H(8)N)(2)(C(12)H(10)NO)(H(2)O)]·0.5C(2)H(6)O(2), the iridium center is coordinated by two N atoms and two C atoms from two 2-(2-pyrid­yl)phenyl (ppy) ligands, one N atom from the N-(1-naphth­yl)acetamide ligand and one water O atom, forming a distorted octa­hedral environment. Mol­ecules are linked by inter­molecular O—H⋯O hydrogen bonds formed by the coordinated water mol­ecule and the amide O atom of the N-(1-naphth­yl)acetamide ligands.
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spelling pubmed-29611672010-12-30 Aqua­[N-(1-naphth­yl)acetamido-κN]bis­[2-(2-pyrid­yl)phenyl-κ(2) N,C (1)]iridium(III) ethyl­ene glycol hemisolvate Fu, Hao Ding, Yuqiang Chen, Guoqing Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Ir(C(11)H(8)N)(2)(C(12)H(10)NO)(H(2)O)]·0.5C(2)H(6)O(2), the iridium center is coordinated by two N atoms and two C atoms from two 2-(2-pyrid­yl)phenyl (ppy) ligands, one N atom from the N-(1-naphth­yl)acetamide ligand and one water O atom, forming a distorted octa­hedral environment. Mol­ecules are linked by inter­molecular O—H⋯O hydrogen bonds formed by the coordinated water mol­ecule and the amide O atom of the N-(1-naphth­yl)acetamide ligands. International Union of Crystallography 2008-04-30 /pmc/articles/PMC2961167/ /pubmed/21202254 http://dx.doi.org/10.1107/S1600536808010040 Text en © Fu et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Fu, Hao
Ding, Yuqiang
Chen, Guoqing
Aqua­[N-(1-naphth­yl)acetamido-κN]bis­[2-(2-pyrid­yl)phenyl-κ(2) N,C (1)]iridium(III) ethyl­ene glycol hemisolvate
title Aqua­[N-(1-naphth­yl)acetamido-κN]bis­[2-(2-pyrid­yl)phenyl-κ(2) N,C (1)]iridium(III) ethyl­ene glycol hemisolvate
title_full Aqua­[N-(1-naphth­yl)acetamido-κN]bis­[2-(2-pyrid­yl)phenyl-κ(2) N,C (1)]iridium(III) ethyl­ene glycol hemisolvate
title_fullStr Aqua­[N-(1-naphth­yl)acetamido-κN]bis­[2-(2-pyrid­yl)phenyl-κ(2) N,C (1)]iridium(III) ethyl­ene glycol hemisolvate
title_full_unstemmed Aqua­[N-(1-naphth­yl)acetamido-κN]bis­[2-(2-pyrid­yl)phenyl-κ(2) N,C (1)]iridium(III) ethyl­ene glycol hemisolvate
title_short Aqua­[N-(1-naphth­yl)acetamido-κN]bis­[2-(2-pyrid­yl)phenyl-κ(2) N,C (1)]iridium(III) ethyl­ene glycol hemisolvate
title_sort aqua­[n-(1-naphth­yl)acetamido-κn]bis­[2-(2-pyrid­yl)phenyl-κ(2) n,c (1)]iridium(iii) ethyl­ene glycol hemisolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961167/
https://www.ncbi.nlm.nih.gov/pubmed/21202254
http://dx.doi.org/10.1107/S1600536808010040
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AT chenguoqing aquan1naphthylacetamidoknbis22pyridylphenylk2nc1iridiumiiiethyleneglycolhemisolvate

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