Tris[2-(deuteriomethyl­sulfan­yl)­phen­yl]­phosphine deuteriochloro­form 0.125-solvate

The title deuterated tripodal phosphine, C(21)H(12)D(9)PS(3)·0.125CDCl(3), crystallizes as two independent mol­ecules, one of which lies on a general position and the other about a threefold rotation axis, and as a deuteriochloro­form solvate. The solvent mol­ecule is disordered about a site of symm...

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Detalles Bibliográficos
Autores principales: Wong, Richard Chee Seng, Ooi, Mei Lee, Sakurai, Hidehiro, Ng, Seik Weng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961173/
https://www.ncbi.nlm.nih.gov/pubmed/21202381
http://dx.doi.org/10.1107/S1600536808010817
Descripción
Sumario:The title deuterated tripodal phosphine, C(21)H(12)D(9)PS(3)·0.125CDCl(3), crystallizes as two independent mol­ecules, one of which lies on a general position and the other about a threefold rotation axis, and as a deuteriochloro­form solvate. The solvent mol­ecule is disordered about a site of symmetry 3, so that the ratio of phosphine to solvent is 8:1. The P atom adopts a pyramidal coordination geometry.

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